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Ligand-Directed Metalation of a Gold Pyrazolate Cluster
[Image: see text] Solid “[AuL]” (HL = 3-[pyrid-2-yl]-5-tertbutyl-1H-pyrazole) can be crystallized as cyclic [Au(3)(μ-L)(3)] and [Au(4)(μ-L)(4)] clusters from different solvents. The crystalline tetramer contains a square Au(4) core with an HT:TH:TH:HT arrangement of ligand substituents, which preorg...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10283019/ https://www.ncbi.nlm.nih.gov/pubmed/37285352 http://dx.doi.org/10.1021/acs.inorgchem.3c01667 |