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Isostructural bridging diferrous chalcogenide cores [Fe(II)(μ-E)Fe(II)] (E = O, S, Se, Te) with decreasing antiferromagnetic coupling down the chalcogenide series
Iron compounds containing a bridging oxo or sulfido moiety are ubiquitous in biological systems, but substitution with the heavier chalcogenides selenium and tellurium, however, is much rarer, with only a few examples reported to date. Here we show that treatment of the ferrous starting material [((...
Autores principales: | Zars, Ethan, Gravogl, Lisa, Gau, Michael R., Carroll, Patrick J., Meyer, Karsten, Mindiola, Daniel J. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10283490/ https://www.ncbi.nlm.nih.gov/pubmed/37350823 http://dx.doi.org/10.1039/d3sc01094e |
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