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Tuning Electrode Reactivity through Organometallic Complexes
[Image: see text] The use of molecularly modified electrodes in catalysis heralds a new paradigm in designing chemical transformations by allowing control of catalytic activity. Herein, we provide an overview of reported methods to develop electrodes functionalized with organometallic complexes and...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10288447/ https://www.ncbi.nlm.nih.gov/pubmed/37293760 http://dx.doi.org/10.1021/acsami.3c01726 |
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author | Shen, Yi Mu, Yu Wang, Dunwei Liu, Chong Diaconescu, Paula L. |
author_facet | Shen, Yi Mu, Yu Wang, Dunwei Liu, Chong Diaconescu, Paula L. |
author_sort | Shen, Yi |
collection | PubMed |
description | [Image: see text] The use of molecularly modified electrodes in catalysis heralds a new paradigm in designing chemical transformations by allowing control of catalytic activity. Herein, we provide an overview of reported methods to develop electrodes functionalized with organometallic complexes and a summary of commonly used techniques for characterizing the electrode surface after immobilization. In addition, we highlight the implications of surface functionalization in catalysis to emphasize the key aspects that should be considered during the development and optimization of functionalized electrodes. Particularly, surface–molecule electronic coupling and electrostatic interactions within a hybrid system are discussed to present effective handles in tuning catalytic activity. We envision that this emerging type of hybrid catalytic system has the potential to combine the advantages of homogeneous catalysis and heterogeneous supports and could be applied to an expanded range of transformations beyond energy conversion. |
format | Online Article Text |
id | pubmed-10288447 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-102884472023-06-24 Tuning Electrode Reactivity through Organometallic Complexes Shen, Yi Mu, Yu Wang, Dunwei Liu, Chong Diaconescu, Paula L. ACS Appl Mater Interfaces [Image: see text] The use of molecularly modified electrodes in catalysis heralds a new paradigm in designing chemical transformations by allowing control of catalytic activity. Herein, we provide an overview of reported methods to develop electrodes functionalized with organometallic complexes and a summary of commonly used techniques for characterizing the electrode surface after immobilization. In addition, we highlight the implications of surface functionalization in catalysis to emphasize the key aspects that should be considered during the development and optimization of functionalized electrodes. Particularly, surface–molecule electronic coupling and electrostatic interactions within a hybrid system are discussed to present effective handles in tuning catalytic activity. We envision that this emerging type of hybrid catalytic system has the potential to combine the advantages of homogeneous catalysis and heterogeneous supports and could be applied to an expanded range of transformations beyond energy conversion. American Chemical Society 2023-06-09 /pmc/articles/PMC10288447/ /pubmed/37293760 http://dx.doi.org/10.1021/acsami.3c01726 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Shen, Yi Mu, Yu Wang, Dunwei Liu, Chong Diaconescu, Paula L. Tuning Electrode Reactivity through Organometallic Complexes |
title | Tuning
Electrode Reactivity through Organometallic
Complexes |
title_full | Tuning
Electrode Reactivity through Organometallic
Complexes |
title_fullStr | Tuning
Electrode Reactivity through Organometallic
Complexes |
title_full_unstemmed | Tuning
Electrode Reactivity through Organometallic
Complexes |
title_short | Tuning
Electrode Reactivity through Organometallic
Complexes |
title_sort | tuning
electrode reactivity through organometallic
complexes |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10288447/ https://www.ncbi.nlm.nih.gov/pubmed/37293760 http://dx.doi.org/10.1021/acsami.3c01726 |
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