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Novel Additive Manufactured Multielectrode Electrochemical Cell with Honeycomb Inspired Design for the Detection of Methyl Parathion in Honey Samples

[Image: see text] The development and increase in the number of crops recently have led to the requirement for greater efficiency in world food production and greater consumption of pesticides. In this context, the widespread use of pesticides has affected the decrease in the population of pollinati...

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Autores principales: Janegitz, Bruno C., Crapnell, Robert D., Roberto de Oliveira, Paulo, Kalinke, Cristiane, Whittingham, Matthew J., Garcia-Miranda Ferrari, Alejandro, Banks, Craig E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10288609/
https://www.ncbi.nlm.nih.gov/pubmed/37360039
http://dx.doi.org/10.1021/acsmeasuresciau.3c00003
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author Janegitz, Bruno C.
Crapnell, Robert D.
Roberto de Oliveira, Paulo
Kalinke, Cristiane
Whittingham, Matthew J.
Garcia-Miranda Ferrari, Alejandro
Banks, Craig E.
author_facet Janegitz, Bruno C.
Crapnell, Robert D.
Roberto de Oliveira, Paulo
Kalinke, Cristiane
Whittingham, Matthew J.
Garcia-Miranda Ferrari, Alejandro
Banks, Craig E.
author_sort Janegitz, Bruno C.
collection PubMed
description [Image: see text] The development and increase in the number of crops recently have led to the requirement for greater efficiency in world food production and greater consumption of pesticides. In this context, the widespread use of pesticides has affected the decrease in the population of pollinating insects and has caused food contamination. Therefore, simple, low-cost, and quick analytical methods can be interesting alternatives for checking the quality of foods such as honey. In this work, we propose a new additively manufactured (3D-printed) device inspired by a honeycomb cell, with 6 working electrodes for the direct electrochemical analysis of methyl parathion by reduction process monitoring in food and environmental samples. Under optimized parameters, the proposed sensor presented a linear range between 0.85 and 19.6 μmol L(–1), with a limit of detection of 0.20 μmol L(–1). The sensors were successfully applied in honey and tap water samples by using the standard addition method. The proposed honeycomb cell made of polylactic acid and commercial conductive filament is easy to construct, and there is no need for chemical treatments to be used. These devices based on 6 working electrodes array are versatile platforms for rapid, highly repeatable analysis in food and environment, capable of performing detection in low concentrations.
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spelling pubmed-102886092023-06-24 Novel Additive Manufactured Multielectrode Electrochemical Cell with Honeycomb Inspired Design for the Detection of Methyl Parathion in Honey Samples Janegitz, Bruno C. Crapnell, Robert D. Roberto de Oliveira, Paulo Kalinke, Cristiane Whittingham, Matthew J. Garcia-Miranda Ferrari, Alejandro Banks, Craig E. ACS Meas Sci Au [Image: see text] The development and increase in the number of crops recently have led to the requirement for greater efficiency in world food production and greater consumption of pesticides. In this context, the widespread use of pesticides has affected the decrease in the population of pollinating insects and has caused food contamination. Therefore, simple, low-cost, and quick analytical methods can be interesting alternatives for checking the quality of foods such as honey. In this work, we propose a new additively manufactured (3D-printed) device inspired by a honeycomb cell, with 6 working electrodes for the direct electrochemical analysis of methyl parathion by reduction process monitoring in food and environmental samples. Under optimized parameters, the proposed sensor presented a linear range between 0.85 and 19.6 μmol L(–1), with a limit of detection of 0.20 μmol L(–1). The sensors were successfully applied in honey and tap water samples by using the standard addition method. The proposed honeycomb cell made of polylactic acid and commercial conductive filament is easy to construct, and there is no need for chemical treatments to be used. These devices based on 6 working electrodes array are versatile platforms for rapid, highly repeatable analysis in food and environment, capable of performing detection in low concentrations. American Chemical Society 2023-04-06 /pmc/articles/PMC10288609/ /pubmed/37360039 http://dx.doi.org/10.1021/acsmeasuresciau.3c00003 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Janegitz, Bruno C.
Crapnell, Robert D.
Roberto de Oliveira, Paulo
Kalinke, Cristiane
Whittingham, Matthew J.
Garcia-Miranda Ferrari, Alejandro
Banks, Craig E.
Novel Additive Manufactured Multielectrode Electrochemical Cell with Honeycomb Inspired Design for the Detection of Methyl Parathion in Honey Samples
title Novel Additive Manufactured Multielectrode Electrochemical Cell with Honeycomb Inspired Design for the Detection of Methyl Parathion in Honey Samples
title_full Novel Additive Manufactured Multielectrode Electrochemical Cell with Honeycomb Inspired Design for the Detection of Methyl Parathion in Honey Samples
title_fullStr Novel Additive Manufactured Multielectrode Electrochemical Cell with Honeycomb Inspired Design for the Detection of Methyl Parathion in Honey Samples
title_full_unstemmed Novel Additive Manufactured Multielectrode Electrochemical Cell with Honeycomb Inspired Design for the Detection of Methyl Parathion in Honey Samples
title_short Novel Additive Manufactured Multielectrode Electrochemical Cell with Honeycomb Inspired Design for the Detection of Methyl Parathion in Honey Samples
title_sort novel additive manufactured multielectrode electrochemical cell with honeycomb inspired design for the detection of methyl parathion in honey samples
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10288609/
https://www.ncbi.nlm.nih.gov/pubmed/37360039
http://dx.doi.org/10.1021/acsmeasuresciau.3c00003
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