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Altering the spectroscopy, electronic structure, and bonding of organometallic curium(III) upon coordination of 4,4′−bipyridine
Structural and electronic characterization of (Cp′(3)Cm)(2)(μ−4,4′−bpy) (Cp′ = trimethylsilylcyclopentadienyl, 4,4′−bpy = 4,4′−bipyridine) is reported and provides a rare example of curium−carbon bonding. Cp′(3)Cm displays unexpectedly low energy emission that is quenched upon coordination by 4,4′−b...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10290646/ https://www.ncbi.nlm.nih.gov/pubmed/37355669 http://dx.doi.org/10.1038/s41467-023-39481-7 |