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Altering the spectroscopy, electronic structure, and bonding of organometallic curium(III) upon coordination of 4,4′−bipyridine

Structural and electronic characterization of (Cp′(3)Cm)(2)(μ−4,4′−bpy) (Cp′ = trimethylsilylcyclopentadienyl, 4,4′−bpy = 4,4′−bipyridine) is reported and provides a rare example of curium−carbon bonding. Cp′(3)Cm displays unexpectedly low energy emission that is quenched upon coordination by 4,4′−b...

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Detalles Bibliográficos
Autores principales:	Long, Brian N., Beltrán-Leíva, María J., Sperling, Joseph M., Poe, Todd N., Celis-Barros, Cristian, Albrecht-Schönzart, Thomas E.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2023
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10290646/ https://www.ncbi.nlm.nih.gov/pubmed/37355669 http://dx.doi.org/10.1038/s41467-023-39481-7

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