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Synthesis of aliphatic nitriles from cyclobutanone oxime mediated by sulfuryl fluoride (SO(2)F(2))
A SO(2)F(2)-mediated ring-opening cross-coupling of cyclobutanone oxime derivatives with alkenes was developed for the construction of a range of δ-olefin-containing aliphatic nitriles with (E)-configuration selectivity. This new method features wide substrate scope, mild conditions, and direct N–O...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Beilstein-Institut
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10291241/ https://www.ncbi.nlm.nih.gov/pubmed/37377774 http://dx.doi.org/10.3762/bjoc.19.68 |