Crystal chemical design, synthesis and characterisation of U(IV)-dominant betafite phases for actinide immobilisation

Crystal chemical design principles were applied to synthesise novel U(4+) dominant and titanium excess betafite phases Ca(1.15(5))U(0.56(4))Zr(0.17(2))Ti(2.19(2))O(7) and Ca(1.10(4))U(0.68(4))Zr(0.15(3))Ti(2.12(2))O(7), in high yield (85–95 wt%), and ceramic density reaching 99% of theoretical. Subs...

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Detalles Bibliográficos
Autores principales: Sun, Shi-Kuan, Mottram, Lucy M., Gouder, Thomas, Stennett, Martin C., Hyatt, Neil C., Corkhill, Claire L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10293183/
https://www.ncbi.nlm.nih.gov/pubmed/37365272
http://dx.doi.org/10.1038/s41598-023-36571-w

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10293183/
https://www.ncbi.nlm.nih.gov/pubmed/37365272
http://dx.doi.org/10.1038/s41598-023-36571-w

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