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Crystal chemical design, synthesis and characterisation of U(IV)-dominant betafite phases for actinide immobilisation
Crystal chemical design principles were applied to synthesise novel U(4+) dominant and titanium excess betafite phases Ca(1.15(5))U(0.56(4))Zr(0.17(2))Ti(2.19(2))O(7) and Ca(1.10(4))U(0.68(4))Zr(0.15(3))Ti(2.12(2))O(7), in high yield (85–95 wt%), and ceramic density reaching 99% of theoretical. Subs...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Nature Publishing Group UK
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10293183/ https://www.ncbi.nlm.nih.gov/pubmed/37365272 http://dx.doi.org/10.1038/s41598-023-36571-w |