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Co-activation for enhanced K-ion storage in battery anodes

The relative natural abundance of potassium and potentially high energy density has established potassium-ion batteries as a promising technology for future large-scale global energy storage. However, the anodes’ low capacity and high discharge platform lead to low energy density, which impedes thei...

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Detalles Bibliográficos
Autores principales: Feng, Yanhong, Lv, Yawei, Fu, Hongwei, Parekh, Mihir, Rao, Apparao M, Wang, He, Tai, Xiaolin, Yi, Xianhui, Lin, Yue, Zhou, Jiang, Lu, Bingan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Oxford University Press 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10306327/
https://www.ncbi.nlm.nih.gov/pubmed/37389185
http://dx.doi.org/10.1093/nsr/nwad118
Descripción
Sumario:The relative natural abundance of potassium and potentially high energy density has established potassium-ion batteries as a promising technology for future large-scale global energy storage. However, the anodes’ low capacity and high discharge platform lead to low energy density, which impedes their rapid development. Herein, we present a possible co-activation mechanism between bismuth (Bi) and tin (Sn) that enhances K-ion storage in battery anodes. The co-activated Bi-Sn anode delivered a high capacity of 634 mAh g(–1), with a discharge plateau as low as 0.35 V, and operated continuously for 500 cycles at a current density of 50 mA g(–1), with a high Coulombic efficiency of 99.2%. This possible co-activation strategy for high potassium storage may be extended to other Na/Zn/Ca/Mg/Al ion battery technologies, thus providing insights into how to improve their energy storage ability.