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Co-activation for enhanced K-ion storage in battery anodes

The relative natural abundance of potassium and potentially high energy density has established potassium-ion batteries as a promising technology for future large-scale global energy storage. However, the anodes’ low capacity and high discharge platform lead to low energy density, which impedes thei...

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Autores principales: Feng, Yanhong, Lv, Yawei, Fu, Hongwei, Parekh, Mihir, Rao, Apparao M, Wang, He, Tai, Xiaolin, Yi, Xianhui, Lin, Yue, Zhou, Jiang, Lu, Bingan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Oxford University Press 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10306327/
https://www.ncbi.nlm.nih.gov/pubmed/37389185
http://dx.doi.org/10.1093/nsr/nwad118
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author Feng, Yanhong
Lv, Yawei
Fu, Hongwei
Parekh, Mihir
Rao, Apparao M
Wang, He
Tai, Xiaolin
Yi, Xianhui
Lin, Yue
Zhou, Jiang
Lu, Bingan
author_facet Feng, Yanhong
Lv, Yawei
Fu, Hongwei
Parekh, Mihir
Rao, Apparao M
Wang, He
Tai, Xiaolin
Yi, Xianhui
Lin, Yue
Zhou, Jiang
Lu, Bingan
author_sort Feng, Yanhong
collection PubMed
description The relative natural abundance of potassium and potentially high energy density has established potassium-ion batteries as a promising technology for future large-scale global energy storage. However, the anodes’ low capacity and high discharge platform lead to low energy density, which impedes their rapid development. Herein, we present a possible co-activation mechanism between bismuth (Bi) and tin (Sn) that enhances K-ion storage in battery anodes. The co-activated Bi-Sn anode delivered a high capacity of 634 mAh g(–1), with a discharge plateau as low as 0.35 V, and operated continuously for 500 cycles at a current density of 50 mA g(–1), with a high Coulombic efficiency of 99.2%. This possible co-activation strategy for high potassium storage may be extended to other Na/Zn/Ca/Mg/Al ion battery technologies, thus providing insights into how to improve their energy storage ability.
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spelling pubmed-103063272023-06-29 Co-activation for enhanced K-ion storage in battery anodes Feng, Yanhong Lv, Yawei Fu, Hongwei Parekh, Mihir Rao, Apparao M Wang, He Tai, Xiaolin Yi, Xianhui Lin, Yue Zhou, Jiang Lu, Bingan Natl Sci Rev Research Article The relative natural abundance of potassium and potentially high energy density has established potassium-ion batteries as a promising technology for future large-scale global energy storage. However, the anodes’ low capacity and high discharge platform lead to low energy density, which impedes their rapid development. Herein, we present a possible co-activation mechanism between bismuth (Bi) and tin (Sn) that enhances K-ion storage in battery anodes. The co-activated Bi-Sn anode delivered a high capacity of 634 mAh g(–1), with a discharge plateau as low as 0.35 V, and operated continuously for 500 cycles at a current density of 50 mA g(–1), with a high Coulombic efficiency of 99.2%. This possible co-activation strategy for high potassium storage may be extended to other Na/Zn/Ca/Mg/Al ion battery technologies, thus providing insights into how to improve their energy storage ability. Oxford University Press 2023-04-25 /pmc/articles/PMC10306327/ /pubmed/37389185 http://dx.doi.org/10.1093/nsr/nwad118 Text en © The Author(s) 2023. Published by Oxford University Press on behalf of China Science Publishing & Media Ltd. https://creativecommons.org/licenses/by/4.0/This is an Open Access article distributed under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse, distribution, and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Article
Feng, Yanhong
Lv, Yawei
Fu, Hongwei
Parekh, Mihir
Rao, Apparao M
Wang, He
Tai, Xiaolin
Yi, Xianhui
Lin, Yue
Zhou, Jiang
Lu, Bingan
Co-activation for enhanced K-ion storage in battery anodes
title Co-activation for enhanced K-ion storage in battery anodes
title_full Co-activation for enhanced K-ion storage in battery anodes
title_fullStr Co-activation for enhanced K-ion storage in battery anodes
title_full_unstemmed Co-activation for enhanced K-ion storage in battery anodes
title_short Co-activation for enhanced K-ion storage in battery anodes
title_sort co-activation for enhanced k-ion storage in battery anodes
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10306327/
https://www.ncbi.nlm.nih.gov/pubmed/37389185
http://dx.doi.org/10.1093/nsr/nwad118
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