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Novel Core/Shell Nylon 6,6/La-TMA MOF Electrospun Nanocomposite Membrane and CO(2) Capture Assessments of the Membrane and Pure La-TMA MOF
[Image: see text] Membrane technology plays a vital, applicable, and essential role in human life and industry. The high adsorption capacity of membranes can be employed for capturing air pollutants and greenhouse gases. In this work, we tried to develop a shaped industrial form of a metal–organic f...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10308571/ https://www.ncbi.nlm.nih.gov/pubmed/37396212 http://dx.doi.org/10.1021/acsomega.3c01616 |
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author | Fateminia, Zohreh Chiniforoshan, Hossein Ghafarinia, Vahid |
author_facet | Fateminia, Zohreh Chiniforoshan, Hossein Ghafarinia, Vahid |
author_sort | Fateminia, Zohreh |
collection | PubMed |
description | [Image: see text] Membrane technology plays a vital, applicable, and essential role in human life and industry. The high adsorption capacity of membranes can be employed for capturing air pollutants and greenhouse gases. In this work, we tried to develop a shaped industrial form of a metal–organic framework as an adsorbent material with the ability to capture CO(2) in the laboratory phase. To do so, a core/shell Nylon 6,6/La-TMA MOF nanofiber composite membrane was synthesized. This organic/inorganic nanomembrane is a kind of nonwoven electrospun fiber that was prepared using the coaxial electrospinning approach. FE-SEM, surface area calculations, nitrogen adsorption/desorption, XRD grazing incidence on thin films, and histogram diagrams were applied to assess the quality of the membrane. This composite membrane as well as pure La-TMA MOF were assessed as CO(2) adsorbent materials. The CO(2) adsorption abilities of the core/shell Nylon 6,6/La-TMA MOF membrane and pure La-TMA MOF were as high as 0.219 and 0.277 mmol/g, respectively. As a result of preparing the nanocomposite membrane from microtubes of La-TMA MOF, the %A of the micro La-TMA MOF (% 43.060) increased to % 48.524 for Nylon 6,6/La-TMA MOF. |
format | Online Article Text |
id | pubmed-10308571 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-103085712023-06-30 Novel Core/Shell Nylon 6,6/La-TMA MOF Electrospun Nanocomposite Membrane and CO(2) Capture Assessments of the Membrane and Pure La-TMA MOF Fateminia, Zohreh Chiniforoshan, Hossein Ghafarinia, Vahid ACS Omega [Image: see text] Membrane technology plays a vital, applicable, and essential role in human life and industry. The high adsorption capacity of membranes can be employed for capturing air pollutants and greenhouse gases. In this work, we tried to develop a shaped industrial form of a metal–organic framework as an adsorbent material with the ability to capture CO(2) in the laboratory phase. To do so, a core/shell Nylon 6,6/La-TMA MOF nanofiber composite membrane was synthesized. This organic/inorganic nanomembrane is a kind of nonwoven electrospun fiber that was prepared using the coaxial electrospinning approach. FE-SEM, surface area calculations, nitrogen adsorption/desorption, XRD grazing incidence on thin films, and histogram diagrams were applied to assess the quality of the membrane. This composite membrane as well as pure La-TMA MOF were assessed as CO(2) adsorbent materials. The CO(2) adsorption abilities of the core/shell Nylon 6,6/La-TMA MOF membrane and pure La-TMA MOF were as high as 0.219 and 0.277 mmol/g, respectively. As a result of preparing the nanocomposite membrane from microtubes of La-TMA MOF, the %A of the micro La-TMA MOF (% 43.060) increased to % 48.524 for Nylon 6,6/La-TMA MOF. American Chemical Society 2023-06-13 /pmc/articles/PMC10308571/ /pubmed/37396212 http://dx.doi.org/10.1021/acsomega.3c01616 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Fateminia, Zohreh Chiniforoshan, Hossein Ghafarinia, Vahid Novel Core/Shell Nylon 6,6/La-TMA MOF Electrospun Nanocomposite Membrane and CO(2) Capture Assessments of the Membrane and Pure La-TMA MOF |
title | Novel Core/Shell
Nylon 6,6/La-TMA MOF Electrospun
Nanocomposite Membrane and CO(2) Capture Assessments of the
Membrane and Pure La-TMA MOF |
title_full | Novel Core/Shell
Nylon 6,6/La-TMA MOF Electrospun
Nanocomposite Membrane and CO(2) Capture Assessments of the
Membrane and Pure La-TMA MOF |
title_fullStr | Novel Core/Shell
Nylon 6,6/La-TMA MOF Electrospun
Nanocomposite Membrane and CO(2) Capture Assessments of the
Membrane and Pure La-TMA MOF |
title_full_unstemmed | Novel Core/Shell
Nylon 6,6/La-TMA MOF Electrospun
Nanocomposite Membrane and CO(2) Capture Assessments of the
Membrane and Pure La-TMA MOF |
title_short | Novel Core/Shell
Nylon 6,6/La-TMA MOF Electrospun
Nanocomposite Membrane and CO(2) Capture Assessments of the
Membrane and Pure La-TMA MOF |
title_sort | novel core/shell
nylon 6,6/la-tma mof electrospun
nanocomposite membrane and co(2) capture assessments of the
membrane and pure la-tma mof |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10308571/ https://www.ncbi.nlm.nih.gov/pubmed/37396212 http://dx.doi.org/10.1021/acsomega.3c01616 |
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