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Novel Core/Shell Nylon 6,6/La-TMA MOF Electrospun Nanocomposite Membrane and CO(2) Capture Assessments of the Membrane and Pure La-TMA MOF

[Image: see text] Membrane technology plays a vital, applicable, and essential role in human life and industry. The high adsorption capacity of membranes can be employed for capturing air pollutants and greenhouse gases. In this work, we tried to develop a shaped industrial form of a metal–organic f...

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Autores principales: Fateminia, Zohreh, Chiniforoshan, Hossein, Ghafarinia, Vahid
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10308571/
https://www.ncbi.nlm.nih.gov/pubmed/37396212
http://dx.doi.org/10.1021/acsomega.3c01616
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author Fateminia, Zohreh
Chiniforoshan, Hossein
Ghafarinia, Vahid
author_facet Fateminia, Zohreh
Chiniforoshan, Hossein
Ghafarinia, Vahid
author_sort Fateminia, Zohreh
collection PubMed
description [Image: see text] Membrane technology plays a vital, applicable, and essential role in human life and industry. The high adsorption capacity of membranes can be employed for capturing air pollutants and greenhouse gases. In this work, we tried to develop a shaped industrial form of a metal–organic framework as an adsorbent material with the ability to capture CO(2) in the laboratory phase. To do so, a core/shell Nylon 6,6/La-TMA MOF nanofiber composite membrane was synthesized. This organic/inorganic nanomembrane is a kind of nonwoven electrospun fiber that was prepared using the coaxial electrospinning approach. FE-SEM, surface area calculations, nitrogen adsorption/desorption, XRD grazing incidence on thin films, and histogram diagrams were applied to assess the quality of the membrane. This composite membrane as well as pure La-TMA MOF were assessed as CO(2) adsorbent materials. The CO(2) adsorption abilities of the core/shell Nylon 6,6/La-TMA MOF membrane and pure La-TMA MOF were as high as 0.219 and 0.277 mmol/g, respectively. As a result of preparing the nanocomposite membrane from microtubes of La-TMA MOF, the %A of the micro La-TMA MOF (% 43.060) increased to % 48.524 for Nylon 6,6/La-TMA MOF.
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spelling pubmed-103085712023-06-30 Novel Core/Shell Nylon 6,6/La-TMA MOF Electrospun Nanocomposite Membrane and CO(2) Capture Assessments of the Membrane and Pure La-TMA MOF Fateminia, Zohreh Chiniforoshan, Hossein Ghafarinia, Vahid ACS Omega [Image: see text] Membrane technology plays a vital, applicable, and essential role in human life and industry. The high adsorption capacity of membranes can be employed for capturing air pollutants and greenhouse gases. In this work, we tried to develop a shaped industrial form of a metal–organic framework as an adsorbent material with the ability to capture CO(2) in the laboratory phase. To do so, a core/shell Nylon 6,6/La-TMA MOF nanofiber composite membrane was synthesized. This organic/inorganic nanomembrane is a kind of nonwoven electrospun fiber that was prepared using the coaxial electrospinning approach. FE-SEM, surface area calculations, nitrogen adsorption/desorption, XRD grazing incidence on thin films, and histogram diagrams were applied to assess the quality of the membrane. This composite membrane as well as pure La-TMA MOF were assessed as CO(2) adsorbent materials. The CO(2) adsorption abilities of the core/shell Nylon 6,6/La-TMA MOF membrane and pure La-TMA MOF were as high as 0.219 and 0.277 mmol/g, respectively. As a result of preparing the nanocomposite membrane from microtubes of La-TMA MOF, the %A of the micro La-TMA MOF (% 43.060) increased to % 48.524 for Nylon 6,6/La-TMA MOF. American Chemical Society 2023-06-13 /pmc/articles/PMC10308571/ /pubmed/37396212 http://dx.doi.org/10.1021/acsomega.3c01616 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Fateminia, Zohreh
Chiniforoshan, Hossein
Ghafarinia, Vahid
Novel Core/Shell Nylon 6,6/La-TMA MOF Electrospun Nanocomposite Membrane and CO(2) Capture Assessments of the Membrane and Pure La-TMA MOF
title Novel Core/Shell Nylon 6,6/La-TMA MOF Electrospun Nanocomposite Membrane and CO(2) Capture Assessments of the Membrane and Pure La-TMA MOF
title_full Novel Core/Shell Nylon 6,6/La-TMA MOF Electrospun Nanocomposite Membrane and CO(2) Capture Assessments of the Membrane and Pure La-TMA MOF
title_fullStr Novel Core/Shell Nylon 6,6/La-TMA MOF Electrospun Nanocomposite Membrane and CO(2) Capture Assessments of the Membrane and Pure La-TMA MOF
title_full_unstemmed Novel Core/Shell Nylon 6,6/La-TMA MOF Electrospun Nanocomposite Membrane and CO(2) Capture Assessments of the Membrane and Pure La-TMA MOF
title_short Novel Core/Shell Nylon 6,6/La-TMA MOF Electrospun Nanocomposite Membrane and CO(2) Capture Assessments of the Membrane and Pure La-TMA MOF
title_sort novel core/shell nylon 6,6/la-tma mof electrospun nanocomposite membrane and co(2) capture assessments of the membrane and pure la-tma mof
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10308571/
https://www.ncbi.nlm.nih.gov/pubmed/37396212
http://dx.doi.org/10.1021/acsomega.3c01616
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