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Magnetic deep eutectic solvent-based dispersive liquid–liquid microextraction for determination of strobilurin fungicides in water, juice, and vinegar by high-performance liquid chromatography
In this study, a magnetic deep eutectic solvent coupled with dispersive liquid–liquid microextraction using high-performance liquid chromatography (MDES-DLLME-HPLC) was developed to detect strobilurin fungicides. The green hydrophobic MDES synthesized by methyltrioctylammonium chloride, ferric chlor...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Elsevier
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10314157/ https://www.ncbi.nlm.nih.gov/pubmed/37397198 http://dx.doi.org/10.1016/j.fochx.2023.100711 |
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author | Wang, Min Zhao, Luyao Niu, Yu Qin, Shu Zhang, Lixin Jia, Liyan Jing, Xu |
author_facet | Wang, Min Zhao, Luyao Niu, Yu Qin, Shu Zhang, Lixin Jia, Liyan Jing, Xu |
author_sort | Wang, Min |
collection | PubMed |
description | In this study, a magnetic deep eutectic solvent coupled with dispersive liquid–liquid microextraction using high-performance liquid chromatography (MDES-DLLME-HPLC) was developed to detect strobilurin fungicides. The green hydrophobic MDES synthesized by methyltrioctylammonium chloride, ferric chloride, and heptanoic acid was used as an extraction solvent, which was dispersed by vortex and separated by an external magnetic field. The use of toxic solvents was avoided, and the separation time was reduced. The best experimental results were obtained through single factor and response surface optimization. The method had a good linear relationship with R(2) > 0.996. The limit of detection (LOD) ranged from 0.001 to 0.002 mg L(−1). The extraction recoveries were 81.9–108.9%. The proposed method was rapid and green, and it has been successfully applied to detection of strobilurin fungicides in water, juice, and vinegar. |
format | Online Article Text |
id | pubmed-10314157 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | Elsevier |
record_format | MEDLINE/PubMed |
spelling | pubmed-103141572023-07-02 Magnetic deep eutectic solvent-based dispersive liquid–liquid microextraction for determination of strobilurin fungicides in water, juice, and vinegar by high-performance liquid chromatography Wang, Min Zhao, Luyao Niu, Yu Qin, Shu Zhang, Lixin Jia, Liyan Jing, Xu Food Chem X Analytical Methods In this study, a magnetic deep eutectic solvent coupled with dispersive liquid–liquid microextraction using high-performance liquid chromatography (MDES-DLLME-HPLC) was developed to detect strobilurin fungicides. The green hydrophobic MDES synthesized by methyltrioctylammonium chloride, ferric chloride, and heptanoic acid was used as an extraction solvent, which was dispersed by vortex and separated by an external magnetic field. The use of toxic solvents was avoided, and the separation time was reduced. The best experimental results were obtained through single factor and response surface optimization. The method had a good linear relationship with R(2) > 0.996. The limit of detection (LOD) ranged from 0.001 to 0.002 mg L(−1). The extraction recoveries were 81.9–108.9%. The proposed method was rapid and green, and it has been successfully applied to detection of strobilurin fungicides in water, juice, and vinegar. Elsevier 2023-05-10 /pmc/articles/PMC10314157/ /pubmed/37397198 http://dx.doi.org/10.1016/j.fochx.2023.100711 Text en © 2023 The Author(s) https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Analytical Methods Wang, Min Zhao, Luyao Niu, Yu Qin, Shu Zhang, Lixin Jia, Liyan Jing, Xu Magnetic deep eutectic solvent-based dispersive liquid–liquid microextraction for determination of strobilurin fungicides in water, juice, and vinegar by high-performance liquid chromatography |
title | Magnetic deep eutectic solvent-based dispersive liquid–liquid microextraction for determination of strobilurin fungicides in water, juice, and vinegar by high-performance liquid chromatography |
title_full | Magnetic deep eutectic solvent-based dispersive liquid–liquid microextraction for determination of strobilurin fungicides in water, juice, and vinegar by high-performance liquid chromatography |
title_fullStr | Magnetic deep eutectic solvent-based dispersive liquid–liquid microextraction for determination of strobilurin fungicides in water, juice, and vinegar by high-performance liquid chromatography |
title_full_unstemmed | Magnetic deep eutectic solvent-based dispersive liquid–liquid microextraction for determination of strobilurin fungicides in water, juice, and vinegar by high-performance liquid chromatography |
title_short | Magnetic deep eutectic solvent-based dispersive liquid–liquid microextraction for determination of strobilurin fungicides in water, juice, and vinegar by high-performance liquid chromatography |
title_sort | magnetic deep eutectic solvent-based dispersive liquid–liquid microextraction for determination of strobilurin fungicides in water, juice, and vinegar by high-performance liquid chromatography |
topic | Analytical Methods |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10314157/ https://www.ncbi.nlm.nih.gov/pubmed/37397198 http://dx.doi.org/10.1016/j.fochx.2023.100711 |
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