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Magnetic deep eutectic solvent-based dispersive liquid–liquid microextraction for determination of strobilurin fungicides in water, juice, and vinegar by high-performance liquid chromatography

In this study, a magnetic deep eutectic solvent coupled with dispersive liquid–liquid microextraction using high-performance liquid chromatography (MDES-DLLME-HPLC) was developed to detect strobilurin fungicides. The green hydrophobic MDES synthesized by methyltrioctylammonium chloride, ferric chlor...

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Autores principales: Wang, Min, Zhao, Luyao, Niu, Yu, Qin, Shu, Zhang, Lixin, Jia, Liyan, Jing, Xu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10314157/
https://www.ncbi.nlm.nih.gov/pubmed/37397198
http://dx.doi.org/10.1016/j.fochx.2023.100711
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author Wang, Min
Zhao, Luyao
Niu, Yu
Qin, Shu
Zhang, Lixin
Jia, Liyan
Jing, Xu
author_facet Wang, Min
Zhao, Luyao
Niu, Yu
Qin, Shu
Zhang, Lixin
Jia, Liyan
Jing, Xu
author_sort Wang, Min
collection PubMed
description In this study, a magnetic deep eutectic solvent coupled with dispersive liquid–liquid microextraction using high-performance liquid chromatography (MDES-DLLME-HPLC) was developed to detect strobilurin fungicides. The green hydrophobic MDES synthesized by methyltrioctylammonium chloride, ferric chloride, and heptanoic acid was used as an extraction solvent, which was dispersed by vortex and separated by an external magnetic field. The use of toxic solvents was avoided, and the separation time was reduced. The best experimental results were obtained through single factor and response surface optimization. The method had a good linear relationship with R(2) > 0.996. The limit of detection (LOD) ranged from 0.001 to 0.002 mg L(−1). The extraction recoveries were 81.9–108.9%. The proposed method was rapid and green, and it has been successfully applied to detection of strobilurin fungicides in water, juice, and vinegar.
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spelling pubmed-103141572023-07-02 Magnetic deep eutectic solvent-based dispersive liquid–liquid microextraction for determination of strobilurin fungicides in water, juice, and vinegar by high-performance liquid chromatography Wang, Min Zhao, Luyao Niu, Yu Qin, Shu Zhang, Lixin Jia, Liyan Jing, Xu Food Chem X Analytical Methods In this study, a magnetic deep eutectic solvent coupled with dispersive liquid–liquid microextraction using high-performance liquid chromatography (MDES-DLLME-HPLC) was developed to detect strobilurin fungicides. The green hydrophobic MDES synthesized by methyltrioctylammonium chloride, ferric chloride, and heptanoic acid was used as an extraction solvent, which was dispersed by vortex and separated by an external magnetic field. The use of toxic solvents was avoided, and the separation time was reduced. The best experimental results were obtained through single factor and response surface optimization. The method had a good linear relationship with R(2) > 0.996. The limit of detection (LOD) ranged from 0.001 to 0.002 mg L(−1). The extraction recoveries were 81.9–108.9%. The proposed method was rapid and green, and it has been successfully applied to detection of strobilurin fungicides in water, juice, and vinegar. Elsevier 2023-05-10 /pmc/articles/PMC10314157/ /pubmed/37397198 http://dx.doi.org/10.1016/j.fochx.2023.100711 Text en © 2023 The Author(s) https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Analytical Methods
Wang, Min
Zhao, Luyao
Niu, Yu
Qin, Shu
Zhang, Lixin
Jia, Liyan
Jing, Xu
Magnetic deep eutectic solvent-based dispersive liquid–liquid microextraction for determination of strobilurin fungicides in water, juice, and vinegar by high-performance liquid chromatography
title Magnetic deep eutectic solvent-based dispersive liquid–liquid microextraction for determination of strobilurin fungicides in water, juice, and vinegar by high-performance liquid chromatography
title_full Magnetic deep eutectic solvent-based dispersive liquid–liquid microextraction for determination of strobilurin fungicides in water, juice, and vinegar by high-performance liquid chromatography
title_fullStr Magnetic deep eutectic solvent-based dispersive liquid–liquid microextraction for determination of strobilurin fungicides in water, juice, and vinegar by high-performance liquid chromatography
title_full_unstemmed Magnetic deep eutectic solvent-based dispersive liquid–liquid microextraction for determination of strobilurin fungicides in water, juice, and vinegar by high-performance liquid chromatography
title_short Magnetic deep eutectic solvent-based dispersive liquid–liquid microextraction for determination of strobilurin fungicides in water, juice, and vinegar by high-performance liquid chromatography
title_sort magnetic deep eutectic solvent-based dispersive liquid–liquid microextraction for determination of strobilurin fungicides in water, juice, and vinegar by high-performance liquid chromatography
topic Analytical Methods
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10314157/
https://www.ncbi.nlm.nih.gov/pubmed/37397198
http://dx.doi.org/10.1016/j.fochx.2023.100711
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