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Tracing the geographical origin of tobacco at two spatial scales by stable isotope and element analyses with chemometrics

Tobacco is a widely cultivated cash crop, but it is often smuggled and sold illegally. Unfortunately, there is currently no way to verify the origin of tobacco in China. In an effort to address this issue, we conducted a study using stable isotopes and elements from 176 tobacco samples at both provi...

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Detalles Bibliográficos
Autores principales: Cui, Lili, Chen, Huan, Yuan, Yuwei, Zhu, Fengpeng, Nie, Jing, Han, Shulei, Fu, Ya'ning, Hou, Hongwei, Hu, Qingyuan, Chen, Zengping
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10314160/
https://www.ncbi.nlm.nih.gov/pubmed/37397212
http://dx.doi.org/10.1016/j.fochx.2023.100716
Descripción
Sumario:Tobacco is a widely cultivated cash crop, but it is often smuggled and sold illegally. Unfortunately, there is currently no way to verify the origin of tobacco in China. In an effort to address this issue, we conducted a study using stable isotopes and elements from 176 tobacco samples at both provincial and municipal scales. Our findings revealed significant differences in δ(13)C, K, Cs, and (208/206)Pb at the provincial-level, and Sr, Se, and Pb at the municipal level. We created a heat map at the municipal level, which showed a similar cluster classification to geographic grouping and provided an initial assessment of tobacco origins. Using OPLS-DA modeling, we achieved a 98.3% accuracy rate for the provincial scale and 97.6% for the municipal scale. It is worth noting that the importance of rankings of variables varied depending on the spatial scale of the evaluation. This study offers the first traceability fingerprint dataset of tobacco and has the potential to combat mislabeling and fraudulent conduct by identifying the geographical origin of tobacco.