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Three-dimensional organization of pyrrolo[3,2-b]pyrrole-based triazine framework using nanostructural spherical carbon: enhancing electrochemical performance of materials for supercapacitors

Covalent triazine-based frameworks have attracted much interest recently due to their high surface area and excellent thermal and electrochemical stabilities. This study shows that covalently immobilizing triazine-based structures on spherical carbon nanostructures results in the organization of mic...

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Autores principales: Hryniewicka, Agnieszka, Breczko, Joanna, Siemiaszko, Gabriela, Papathanassiou, Anthony N., Góra-Marek, Kinga, Tarach, Karolina A., Brzezinski, Krzysztof, Ilnicka, Anna, Terzyk, Artur P., Markiewicz, Karolina H., Echegoyen, Luis, Plonska-Brzezinska, Marta E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10318046/
https://www.ncbi.nlm.nih.gov/pubmed/37400511
http://dx.doi.org/10.1038/s41598-023-37708-7
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author Hryniewicka, Agnieszka
Breczko, Joanna
Siemiaszko, Gabriela
Papathanassiou, Anthony N.
Góra-Marek, Kinga
Tarach, Karolina A.
Brzezinski, Krzysztof
Ilnicka, Anna
Terzyk, Artur P.
Markiewicz, Karolina H.
Echegoyen, Luis
Plonska-Brzezinska, Marta E.
author_facet Hryniewicka, Agnieszka
Breczko, Joanna
Siemiaszko, Gabriela
Papathanassiou, Anthony N.
Góra-Marek, Kinga
Tarach, Karolina A.
Brzezinski, Krzysztof
Ilnicka, Anna
Terzyk, Artur P.
Markiewicz, Karolina H.
Echegoyen, Luis
Plonska-Brzezinska, Marta E.
author_sort Hryniewicka, Agnieszka
collection PubMed
description Covalent triazine-based frameworks have attracted much interest recently due to their high surface area and excellent thermal and electrochemical stabilities. This study shows that covalently immobilizing triazine-based structures on spherical carbon nanostructures results in the organization of micro- and mesopores in a three-dimensional manner. We selected the nitrile-functionalized pyrrolo[3,2-b]pyrrole unit to form triazine rings to construct a covalent organic framework. Combining spherical carbon nanostructures with the triazine framework produced a material with unique physicochemical properties, exhibiting the highest specific capacitance value of 638 F g(−1) in aqueous acidic solutions. This phenomenon is attributed to many factors. The material exhibits a large surface area, a high content of micropores, a high content of graphitic N, and N-sites with basicity and semi-crystalline character. Thanks to the high structural organization and reproducibility, and remarkably high specific capacitance, these systems are promising materials for use in electrochemistry. For the first time, hybrid systems containing triazine-based frameworks and carbon nano-onions were used as electrodes for supercapacitors.
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spelling pubmed-103180462023-07-05 Three-dimensional organization of pyrrolo[3,2-b]pyrrole-based triazine framework using nanostructural spherical carbon: enhancing electrochemical performance of materials for supercapacitors Hryniewicka, Agnieszka Breczko, Joanna Siemiaszko, Gabriela Papathanassiou, Anthony N. Góra-Marek, Kinga Tarach, Karolina A. Brzezinski, Krzysztof Ilnicka, Anna Terzyk, Artur P. Markiewicz, Karolina H. Echegoyen, Luis Plonska-Brzezinska, Marta E. Sci Rep Article Covalent triazine-based frameworks have attracted much interest recently due to their high surface area and excellent thermal and electrochemical stabilities. This study shows that covalently immobilizing triazine-based structures on spherical carbon nanostructures results in the organization of micro- and mesopores in a three-dimensional manner. We selected the nitrile-functionalized pyrrolo[3,2-b]pyrrole unit to form triazine rings to construct a covalent organic framework. Combining spherical carbon nanostructures with the triazine framework produced a material with unique physicochemical properties, exhibiting the highest specific capacitance value of 638 F g(−1) in aqueous acidic solutions. This phenomenon is attributed to many factors. The material exhibits a large surface area, a high content of micropores, a high content of graphitic N, and N-sites with basicity and semi-crystalline character. Thanks to the high structural organization and reproducibility, and remarkably high specific capacitance, these systems are promising materials for use in electrochemistry. For the first time, hybrid systems containing triazine-based frameworks and carbon nano-onions were used as electrodes for supercapacitors. Nature Publishing Group UK 2023-07-03 /pmc/articles/PMC10318046/ /pubmed/37400511 http://dx.doi.org/10.1038/s41598-023-37708-7 Text en © The Author(s) 2023 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Article
Hryniewicka, Agnieszka
Breczko, Joanna
Siemiaszko, Gabriela
Papathanassiou, Anthony N.
Góra-Marek, Kinga
Tarach, Karolina A.
Brzezinski, Krzysztof
Ilnicka, Anna
Terzyk, Artur P.
Markiewicz, Karolina H.
Echegoyen, Luis
Plonska-Brzezinska, Marta E.
Three-dimensional organization of pyrrolo[3,2-b]pyrrole-based triazine framework using nanostructural spherical carbon: enhancing electrochemical performance of materials for supercapacitors
title Three-dimensional organization of pyrrolo[3,2-b]pyrrole-based triazine framework using nanostructural spherical carbon: enhancing electrochemical performance of materials for supercapacitors
title_full Three-dimensional organization of pyrrolo[3,2-b]pyrrole-based triazine framework using nanostructural spherical carbon: enhancing electrochemical performance of materials for supercapacitors
title_fullStr Three-dimensional organization of pyrrolo[3,2-b]pyrrole-based triazine framework using nanostructural spherical carbon: enhancing electrochemical performance of materials for supercapacitors
title_full_unstemmed Three-dimensional organization of pyrrolo[3,2-b]pyrrole-based triazine framework using nanostructural spherical carbon: enhancing electrochemical performance of materials for supercapacitors
title_short Three-dimensional organization of pyrrolo[3,2-b]pyrrole-based triazine framework using nanostructural spherical carbon: enhancing electrochemical performance of materials for supercapacitors
title_sort three-dimensional organization of pyrrolo[3,2-b]pyrrole-based triazine framework using nanostructural spherical carbon: enhancing electrochemical performance of materials for supercapacitors
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10318046/
https://www.ncbi.nlm.nih.gov/pubmed/37400511
http://dx.doi.org/10.1038/s41598-023-37708-7
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