Valence tautomerism in a cobalt–dioxolene complex containing an imidazolic ancillary ligand

This work reports the synthesis, structural, spectroscopic and magnetic investigation of two complexes, [Co(bmimapy)(3,5-DTBCat)]PF(6)·H(2)O (1) and [Co(bmimapy)(TCCat)]PF(6)·H(2)O (2), where bmimapy is an imidazolic tetradentate ancillary ligand and 3,5-DTBCat and TCCat are the 3,5-di-tert-butyl-ca...

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Detalles Bibliográficos
Autores principales: Moledo Vicente Guedes, Anderson, Sodré de Abreu, Leandro, Maldonado, Igor Antunes Vogel, Fernandes, William Silva, Cardozo, Thiago Messias, A. Allão Cassaro, Rafael, Scarpellini, Marciela, Poneti, Giordano
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10318486/
https://www.ncbi.nlm.nih.gov/pubmed/37409047
http://dx.doi.org/10.1039/d3ra03235c

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