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Tunable three-dimensional architecture of nematic disclination lines

Disclination lines play a key role in many physical processes, from the fracture of materials to the formation of the early universe. Achieving versatile control over disclinations is key to developing novel electro-optical devices, programmable origami, directed colloidal assembly, and controlling...

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Autores principales: Modin, Alvin, Ash, Biswarup, Ishimoto, Kelsey, Leheny, Robert L., Serra, Francesca, Aharoni, Hillel
Formato: Online Artículo Texto
Lenguaje:English
Publicado: National Academy of Sciences 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10319030/
https://www.ncbi.nlm.nih.gov/pubmed/37364119
http://dx.doi.org/10.1073/pnas.2300833120
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author Modin, Alvin
Ash, Biswarup
Ishimoto, Kelsey
Leheny, Robert L.
Serra, Francesca
Aharoni, Hillel
author_facet Modin, Alvin
Ash, Biswarup
Ishimoto, Kelsey
Leheny, Robert L.
Serra, Francesca
Aharoni, Hillel
author_sort Modin, Alvin
collection PubMed
description Disclination lines play a key role in many physical processes, from the fracture of materials to the formation of the early universe. Achieving versatile control over disclinations is key to developing novel electro-optical devices, programmable origami, directed colloidal assembly, and controlling active matter. Here, we introduce a theoretical framework to tailor three-dimensional disclination architecture in nematic liquid crystals experimentally. We produce quantitative predictions for the connectivity and shape of disclination lines found in nematics confined between two thinly spaced glass substrates with strong patterned planar anchoring. By drawing an analogy between nematic liquid crystals and magnetostatics, we find that i) disclination lines connect defects with the same topological charge on opposite surfaces and ii) disclination lines are attracted to regions of the highest twist. Using polarized light to pattern the in-plane alignment of liquid crystal molecules, we test these predictions experimentally and identify critical parameters that tune the disclination lines’ curvature. We verify our predictions with computer simulations and find nondimensional parameters enabling us to match experiments and simulations at different length scales. Our work provides a powerful method to understand and practically control defect lines in nematic liquid crystals.
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spelling pubmed-103190302023-07-05 Tunable three-dimensional architecture of nematic disclination lines Modin, Alvin Ash, Biswarup Ishimoto, Kelsey Leheny, Robert L. Serra, Francesca Aharoni, Hillel Proc Natl Acad Sci U S A Physical Sciences Disclination lines play a key role in many physical processes, from the fracture of materials to the formation of the early universe. Achieving versatile control over disclinations is key to developing novel electro-optical devices, programmable origami, directed colloidal assembly, and controlling active matter. Here, we introduce a theoretical framework to tailor three-dimensional disclination architecture in nematic liquid crystals experimentally. We produce quantitative predictions for the connectivity and shape of disclination lines found in nematics confined between two thinly spaced glass substrates with strong patterned planar anchoring. By drawing an analogy between nematic liquid crystals and magnetostatics, we find that i) disclination lines connect defects with the same topological charge on opposite surfaces and ii) disclination lines are attracted to regions of the highest twist. Using polarized light to pattern the in-plane alignment of liquid crystal molecules, we test these predictions experimentally and identify critical parameters that tune the disclination lines’ curvature. We verify our predictions with computer simulations and find nondimensional parameters enabling us to match experiments and simulations at different length scales. Our work provides a powerful method to understand and practically control defect lines in nematic liquid crystals. National Academy of Sciences 2023-06-26 2023-07-04 /pmc/articles/PMC10319030/ /pubmed/37364119 http://dx.doi.org/10.1073/pnas.2300833120 Text en Copyright © 2023 the Author(s). Published by PNAS. https://creativecommons.org/licenses/by-nc-nd/4.0/This open access article is distributed under Creative Commons Attribution-NonCommercial-NoDerivatives License 4.0 (CC BY-NC-ND) (https://creativecommons.org/licenses/by-nc-nd/4.0/) .
spellingShingle Physical Sciences
Modin, Alvin
Ash, Biswarup
Ishimoto, Kelsey
Leheny, Robert L.
Serra, Francesca
Aharoni, Hillel
Tunable three-dimensional architecture of nematic disclination lines
title Tunable three-dimensional architecture of nematic disclination lines
title_full Tunable three-dimensional architecture of nematic disclination lines
title_fullStr Tunable three-dimensional architecture of nematic disclination lines
title_full_unstemmed Tunable three-dimensional architecture of nematic disclination lines
title_short Tunable three-dimensional architecture of nematic disclination lines
title_sort tunable three-dimensional architecture of nematic disclination lines
topic Physical Sciences
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10319030/
https://www.ncbi.nlm.nih.gov/pubmed/37364119
http://dx.doi.org/10.1073/pnas.2300833120
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