Photocrystallography of [Ru(bpy)(2)(dmso)(2)](2+) reveals an O-bonded metastable state

We report the first instance of observing the phototriggered isomerization of dmso ligands on a bis sulfoxide complex, [Ru(bpy)(2)(dmso)(2)], in the crystalline solid state. The solid-state UV-vis spectrum of the crystal demonstrates an increase in optical density around 550 nm after irradiation, wh...

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Detalles Bibliográficos
Autores principales: Marr, Zoe Y., Thapa Magar, Rajani, Fournier, Bertrand, Benedict, Jason B., Rack, Jeffrey J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10321476/
https://www.ncbi.nlm.nih.gov/pubmed/37416725
http://dx.doi.org/10.1039/d3sc01526b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10321476/
https://www.ncbi.nlm.nih.gov/pubmed/37416725
http://dx.doi.org/10.1039/d3sc01526b

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