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Photocrystallography of [Ru(bpy)(2)(dmso)(2)](2+) reveals an O-bonded metastable state
We report the first instance of observing the phototriggered isomerization of dmso ligands on a bis sulfoxide complex, [Ru(bpy)(2)(dmso)(2)], in the crystalline solid state. The solid-state UV-vis spectrum of the crystal demonstrates an increase in optical density around 550 nm after irradiation, wh...
Autores principales: | Marr, Zoe Y., Thapa Magar, Rajani, Fournier, Bertrand, Benedict, Jason B., Rack, Jeffrey J. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10321476/ https://www.ncbi.nlm.nih.gov/pubmed/37416725 http://dx.doi.org/10.1039/d3sc01526b |
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