Synthesis and characterization of visible-light-driven novel CuTa(2)O(6) as a promising practical photocatalyst

In this work, the novel CuTa(2)O(6) phase was successfully synthesized by the hydrothermal and followed by the calcination process. The X-ray diffraction pattern confirms the formation of different phases. At a low temperature, CuTa(2)O(6) exhibits the orthorhombic phase, whereas, at a higher temperature, it underwent a phase transition to a cubic crystal structure. X-ray photoelectron spectroscopic results suggest the presence of all the elements (Cu, Ta, and O). The optical studies were carried out using a UV-Vis DRS spectrophotometer. FESEM images confirm the spherical-shaped particles for the sample annealed at a high temperature. The local atomic and electronic structures around Cu and the contribution of the Cu oxidation state in the CuTa(2)O(6) system were determined by X-ray absorption spectroscopy. To investigate the effective usage of CuTa(2)O(6) in treating wastewater, its photocatalytic activity was investigated by evaluating its use in the photodegradation of MO dye under visible light irradiation. Moreover, the prepared CuTa(2)O(6) photocatalyst exhibits significant photocatalytic activity in the degradation of MO dye and shows excellent stability; it is therefore a promising material for potential use in a practical photocatalyst. The CuTa(2)O(6) photocatalyst suggests an alternative avenue of research into effective photo-catalysts for solar hydrogen water splitting.