Reductive Hydrogenation of Sulfido-Bridged Tantalum Alkyl Complexes: A Mechanistic Insight

[Image: see text] Hydrogenolysis of a series of alkyl sulfido-bridged tantalum(IV) dinuclear complexes [Ta(η(5)-C(5)Me(5))R(μ-S)](2) [R = Me, nBu (1), Et, CH(2)SiMe(3), C(3)H(5), Ph, CH(2)Ph (2), p-MeC(6)H(4)CH(2) (3)] has led quantitatively to the Ta(III) tetrametallic sulfide cluster [Ta(η(5)-C(5)...

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Detalles Bibliográficos
Autores principales: Carbó, Jorge J., Gómez, Manuel, Hernández-Prieto, Cristina, Hernán-Gómez, Alberto, Martín, Avelino, Mena, Miguel, Puiggalí-Jou, Jordi, Ricart, Josep M., Santamaría, Cristina
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10324320/
https://www.ncbi.nlm.nih.gov/pubmed/37319404
http://dx.doi.org/10.1021/acs.inorgchem.3c00043

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