Iron(II) Complex with a Silacycle-Bridged Biaryl-Based Ligand

[Image: see text] Treatment of 2,6-dimethyl-1,1′-biphenyl-substituted chlorosilane with potassium followed by FeBr(2)/TMEDA led to the formation of an iron(II) monobromide complex supported by a TMEDA ligand and a carbanion-based ligand containing a six-membered silacycle-bridged biphenyl skeleton....

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Detalles Bibliográficos
Autores principales: Suga, Yuto, Sunada, Yusuke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10324383/
https://www.ncbi.nlm.nih.gov/pubmed/37426232
http://dx.doi.org/10.1021/acsomega.3c03161
Descripción
Sumario:[Image: see text] Treatment of 2,6-dimethyl-1,1′-biphenyl-substituted chlorosilane with potassium followed by FeBr(2)/TMEDA led to the formation of an iron(II) monobromide complex supported by a TMEDA ligand and a carbanion-based ligand containing a six-membered silacycle-bridged biphenyl skeleton. The obtained complex crystallized as a racemic mixture of (Sa, S) and (Ra, R) forms, in which the dihedral angle of the two phenyl rings of the biphenyl moiety was ∼43°.

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