Iron(II) Complex with a Silacycle-Bridged Biaryl-Based Ligand

[Image: see text] Treatment of 2,6-dimethyl-1,1′-biphenyl-substituted chlorosilane with potassium followed by FeBr(2)/TMEDA led to the formation of an iron(II) monobromide complex supported by a TMEDA ligand and a carbanion-based ligand containing a six-membered silacycle-bridged biphenyl skeleton....

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Autores principales: Suga, Yuto, Sunada, Yusuke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10324383/
https://www.ncbi.nlm.nih.gov/pubmed/37426232
http://dx.doi.org/10.1021/acsomega.3c03161
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author Suga, Yuto
Sunada, Yusuke
author_facet Suga, Yuto
Sunada, Yusuke
author_sort Suga, Yuto
collection PubMed
description [Image: see text] Treatment of 2,6-dimethyl-1,1′-biphenyl-substituted chlorosilane with potassium followed by FeBr(2)/TMEDA led to the formation of an iron(II) monobromide complex supported by a TMEDA ligand and a carbanion-based ligand containing a six-membered silacycle-bridged biphenyl skeleton. The obtained complex crystallized as a racemic mixture of (Sa, S) and (Ra, R) forms, in which the dihedral angle of the two phenyl rings of the biphenyl moiety was ∼43°.
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spelling pubmed-103243832023-07-07 Iron(II) Complex with a Silacycle-Bridged Biaryl-Based Ligand Suga, Yuto Sunada, Yusuke ACS Omega [Image: see text] Treatment of 2,6-dimethyl-1,1′-biphenyl-substituted chlorosilane with potassium followed by FeBr(2)/TMEDA led to the formation of an iron(II) monobromide complex supported by a TMEDA ligand and a carbanion-based ligand containing a six-membered silacycle-bridged biphenyl skeleton. The obtained complex crystallized as a racemic mixture of (Sa, S) and (Ra, R) forms, in which the dihedral angle of the two phenyl rings of the biphenyl moiety was ∼43°. American Chemical Society 2023-06-23 /pmc/articles/PMC10324383/ /pubmed/37426232 http://dx.doi.org/10.1021/acsomega.3c03161 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Suga, Yuto
Sunada, Yusuke
Iron(II) Complex with a Silacycle-Bridged Biaryl-Based Ligand
title Iron(II) Complex with a Silacycle-Bridged Biaryl-Based Ligand
title_full Iron(II) Complex with a Silacycle-Bridged Biaryl-Based Ligand
title_fullStr Iron(II) Complex with a Silacycle-Bridged Biaryl-Based Ligand
title_full_unstemmed Iron(II) Complex with a Silacycle-Bridged Biaryl-Based Ligand
title_short Iron(II) Complex with a Silacycle-Bridged Biaryl-Based Ligand
title_sort iron(ii) complex with a silacycle-bridged biaryl-based ligand
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10324383/
https://www.ncbi.nlm.nih.gov/pubmed/37426232
http://dx.doi.org/10.1021/acsomega.3c03161
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AT sunadayusuke ironiicomplexwithasilacyclebridgedbiarylbasedligand

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