The Intracavity Extension of 28-Hetero-2,7-naphthiporphyrins in Reactions with Alkylamines

[Image: see text] The 28-hetero-2,7-naphthiporphyrins reacted with triethylamine and diethylamine to form nonaromatic intracavity-extended macrocycles incorporating naphthodihydro-2H-pyran, naphthotetrahydropyridine, and naphthopyrrolotetrahydro-1H-azepine moieties. The new macrocycles were characte...

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Detalles Bibliográficos
Autores principales: Ślusarek, Katarzyna, Perdek, Jędrzej P., Białońska, Agata, Grzelczak, Rafał A., Szyszko, Bartosz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10324391/
https://www.ncbi.nlm.nih.gov/pubmed/37345966
http://dx.doi.org/10.1021/acs.orglett.3c01715
Descripción
Sumario:[Image: see text] The 28-hetero-2,7-naphthiporphyrins reacted with triethylamine and diethylamine to form nonaromatic intracavity-extended macrocycles incorporating naphthodihydro-2H-pyran, naphthotetrahydropyridine, and naphthopyrrolotetrahydro-1H-azepine moieties. The new macrocycles were characterized in solution by means of NMR and UV–vis spectroscopy and in the solid state by XRD.

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