Variable temperature kinetic isotope effects demonstrate extensive tunnelling in the C–H activation reactivity of a transition metal-oxo complex

There has been recent interest about how the rates of concerted proton electron transfer (CPET) are affected by the thermodynamic parameters of intermediates from stepwise PT or ET reactions. Semiclassical arguments have been used to explain these trends despite the importance of quantum mechanical...

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Detalles Bibliográficos
Autores principales: Schneider, Joseph E., Goetz, McKenna K., Anderson, John S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10324459/
https://www.ncbi.nlm.nih.gov/pubmed/37340816
http://dx.doi.org/10.1039/d3cc02130k

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10324459/
https://www.ncbi.nlm.nih.gov/pubmed/37340816
http://dx.doi.org/10.1039/d3cc02130k

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