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Variable temperature kinetic isotope effects demonstrate extensive tunnelling in the C–H activation reactivity of a transition metal-oxo complex
There has been recent interest about how the rates of concerted proton electron transfer (CPET) are affected by the thermodynamic parameters of intermediates from stepwise PT or ET reactions. Semiclassical arguments have been used to explain these trends despite the importance of quantum mechanical...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10324459/ https://www.ncbi.nlm.nih.gov/pubmed/37340816 http://dx.doi.org/10.1039/d3cc02130k |