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A systematic study of the interplay between guest molecule structure and intermolecular interactions in crystalline sponges

Utilization of the crystalline sponge {[(ZnI(2))(3)(tpt)(2)·x(solvent)]( n )} method has enabled characterization of a novel family of synthetic organic oils. The systematic structural differences and diversity of functional groups offered by 13 related molecular adsorbates provide a detailed quanti...

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Detalles Bibliográficos
Autores principales: Carroll, Robert C., Harrowven, David C., Pearce, James E., Coles, Simon J.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10324488/
https://www.ncbi.nlm.nih.gov/pubmed/37409807
http://dx.doi.org/10.1107/S2052252523005146
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author Carroll, Robert C.
Harrowven, David C.
Pearce, James E.
Coles, Simon J.
author_facet Carroll, Robert C.
Harrowven, David C.
Pearce, James E.
Coles, Simon J.
author_sort Carroll, Robert C.
collection PubMed
description Utilization of the crystalline sponge {[(ZnI(2))(3)(tpt)(2)·x(solvent)]( n )} method has enabled characterization of a novel family of synthetic organic oils. The systematic structural differences and diversity of functional groups offered by 13 related molecular adsorbates provide a detailed quantitative understanding of the relationship between the guest structure, its conformation, and the type of intermolecular interactions adopted with neighbouring guests and the host framework. This analysis is extended to assess the connection of these factors to the resulting quality indicators for a particular molecular structure elucidation.
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spelling pubmed-103244882023-07-07 A systematic study of the interplay between guest molecule structure and intermolecular interactions in crystalline sponges Carroll, Robert C. Harrowven, David C. Pearce, James E. Coles, Simon J. IUCrJ Research Papers Utilization of the crystalline sponge {[(ZnI(2))(3)(tpt)(2)·x(solvent)]( n )} method has enabled characterization of a novel family of synthetic organic oils. The systematic structural differences and diversity of functional groups offered by 13 related molecular adsorbates provide a detailed quantitative understanding of the relationship between the guest structure, its conformation, and the type of intermolecular interactions adopted with neighbouring guests and the host framework. This analysis is extended to assess the connection of these factors to the resulting quality indicators for a particular molecular structure elucidation. International Union of Crystallography 2023-07-01 /pmc/articles/PMC10324488/ /pubmed/37409807 http://dx.doi.org/10.1107/S2052252523005146 Text en © Robert C. Carroll et al. 2023 https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Research Papers
Carroll, Robert C.
Harrowven, David C.
Pearce, James E.
Coles, Simon J.
A systematic study of the interplay between guest molecule structure and intermolecular interactions in crystalline sponges
title A systematic study of the interplay between guest molecule structure and intermolecular interactions in crystalline sponges
title_full A systematic study of the interplay between guest molecule structure and intermolecular interactions in crystalline sponges
title_fullStr A systematic study of the interplay between guest molecule structure and intermolecular interactions in crystalline sponges
title_full_unstemmed A systematic study of the interplay between guest molecule structure and intermolecular interactions in crystalline sponges
title_short A systematic study of the interplay between guest molecule structure and intermolecular interactions in crystalline sponges
title_sort systematic study of the interplay between guest molecule structure and intermolecular interactions in crystalline sponges
topic Research Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10324488/
https://www.ncbi.nlm.nih.gov/pubmed/37409807
http://dx.doi.org/10.1107/S2052252523005146
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