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Adsorption and mitigation impact of the monosodium glutamate (C(5)H(8)NO(4)Na) bio-molecules on the steel rebar corrosion in the chloride-contaminated simulated concrete pore solution

Corrosion has caused significant annual costs for building construction and civil architectural designs. In this study, Monosodium glutamate (GLU) was proposed as a potential candidate for long-lasting corrosion inhibition to slow down the rate of corrosion in the concrete pore environment. In this...

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Autores principales: Mohammadkhah, Sahel, Dehghani, Ali, Ramezanzadeh, Bahram
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10333273/
https://www.ncbi.nlm.nih.gov/pubmed/37430026
http://dx.doi.org/10.1038/s41598-023-38111-y
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author Mohammadkhah, Sahel
Dehghani, Ali
Ramezanzadeh, Bahram
author_facet Mohammadkhah, Sahel
Dehghani, Ali
Ramezanzadeh, Bahram
author_sort Mohammadkhah, Sahel
collection PubMed
description Corrosion has caused significant annual costs for building construction and civil architectural designs. In this study, Monosodium glutamate (GLU) was proposed as a potential candidate for long-lasting corrosion inhibition to slow down the rate of corrosion in the concrete pore environment. In this regard, the electrochemical and morphological properties of the various GLU concentrated systems between 1 to 5 wt% in the simulated concrete pore solution media were investigated. According to the EIS results, adding 4 wt% of GLU could reduce the mild steel corrosion process by 86% through a mixed inhibition mechanism. Also, the polarization records represented that the samples’ corrosion current density was diminished to 0.169 µA cm(−2) after the addition of 4 wt% GLU into the harsh environment. Using the FE-SEM method, the growth of the GLU layer over the metal substrate was demonstrated. The results of spectroscopic methods, i.e., Raman and GIXRD, demonstrated that GLU molecules were successfully adsorbed over the surface of the metal. Contact angle test outcomes showed that by increasing the GLU concentration to its optimum level (4 wt%), the surface hydrophobicity was dramatically raised to 62°.
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spelling pubmed-103332732023-07-12 Adsorption and mitigation impact of the monosodium glutamate (C(5)H(8)NO(4)Na) bio-molecules on the steel rebar corrosion in the chloride-contaminated simulated concrete pore solution Mohammadkhah, Sahel Dehghani, Ali Ramezanzadeh, Bahram Sci Rep Article Corrosion has caused significant annual costs for building construction and civil architectural designs. In this study, Monosodium glutamate (GLU) was proposed as a potential candidate for long-lasting corrosion inhibition to slow down the rate of corrosion in the concrete pore environment. In this regard, the electrochemical and morphological properties of the various GLU concentrated systems between 1 to 5 wt% in the simulated concrete pore solution media were investigated. According to the EIS results, adding 4 wt% of GLU could reduce the mild steel corrosion process by 86% through a mixed inhibition mechanism. Also, the polarization records represented that the samples’ corrosion current density was diminished to 0.169 µA cm(−2) after the addition of 4 wt% GLU into the harsh environment. Using the FE-SEM method, the growth of the GLU layer over the metal substrate was demonstrated. The results of spectroscopic methods, i.e., Raman and GIXRD, demonstrated that GLU molecules were successfully adsorbed over the surface of the metal. Contact angle test outcomes showed that by increasing the GLU concentration to its optimum level (4 wt%), the surface hydrophobicity was dramatically raised to 62°. Nature Publishing Group UK 2023-07-10 /pmc/articles/PMC10333273/ /pubmed/37430026 http://dx.doi.org/10.1038/s41598-023-38111-y Text en © The Author(s) 2023 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) .
spellingShingle Article
Mohammadkhah, Sahel
Dehghani, Ali
Ramezanzadeh, Bahram
Adsorption and mitigation impact of the monosodium glutamate (C(5)H(8)NO(4)Na) bio-molecules on the steel rebar corrosion in the chloride-contaminated simulated concrete pore solution
title Adsorption and mitigation impact of the monosodium glutamate (C(5)H(8)NO(4)Na) bio-molecules on the steel rebar corrosion in the chloride-contaminated simulated concrete pore solution
title_full Adsorption and mitigation impact of the monosodium glutamate (C(5)H(8)NO(4)Na) bio-molecules on the steel rebar corrosion in the chloride-contaminated simulated concrete pore solution
title_fullStr Adsorption and mitigation impact of the monosodium glutamate (C(5)H(8)NO(4)Na) bio-molecules on the steel rebar corrosion in the chloride-contaminated simulated concrete pore solution
title_full_unstemmed Adsorption and mitigation impact of the monosodium glutamate (C(5)H(8)NO(4)Na) bio-molecules on the steel rebar corrosion in the chloride-contaminated simulated concrete pore solution
title_short Adsorption and mitigation impact of the monosodium glutamate (C(5)H(8)NO(4)Na) bio-molecules on the steel rebar corrosion in the chloride-contaminated simulated concrete pore solution
title_sort adsorption and mitigation impact of the monosodium glutamate (c(5)h(8)no(4)na) bio-molecules on the steel rebar corrosion in the chloride-contaminated simulated concrete pore solution
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10333273/
https://www.ncbi.nlm.nih.gov/pubmed/37430026
http://dx.doi.org/10.1038/s41598-023-38111-y
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