Cargando…
A Light-Promoted Innate Trifluoromethylation of Pyridones and Related N-Heteroarenes
[Image: see text] We report a practical, light-mediated perfluoroalkylation using Langlois’ reagent (sodium trifluoromethylsulfinate) that proceeds in the absence of any photocatalyst or additives. This method has allowed for the facile functionalization of pyridones and related N-heteroarenes such...
Autores principales: | Dang-Nguyen, Ashley, Legaspi, Kristine C., McCarty, Connor T., Smith, Diane K., Gustafson, Jeffrey |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
|
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10334463/ https://www.ncbi.nlm.nih.gov/pubmed/37377204 http://dx.doi.org/10.1021/acs.orglett.3c01710 |
Ejemplares similares
-
Cobalt-electrocatalytic C–H hydroxyalkylation of N-heteroarenes with trifluoromethyl ketones
por: He, Tianyu, et al.
Publicado: (2022) -
Ligand- and Additive-Free 2-Position-Selective Trifluoromethylation of Heteroarenes Under Ambient Conditions
por: Shi, Xiaolin, et al.
Publicado: (2019) -
Catalytic C–H
Trifluoromethylation of Arenes
and Heteroarenes via Visible Light Photoexcitation of a Co(III)–CF(3) Complex
por: Kuehner, Christopher S., et al.
Publicado: (2023) -
Reactions of Trifluorotriacetic Acid Lactone and Hexafluorodehydroacetic Acid with Amines: Synthesis of Trifluoromethylated 4-Pyridones and Aminoenones
por: Fedin, Vladislav V., et al.
Publicado: (2022) -
Nickel-catalyzed decarbonylation of N-acylated N-heteroarenes
por: Morioka, Toshifumi, et al.
Publicado: (2019)