Modulable Photocatalyzed Strategies for the Synthesis of α-C-Glycosyl Alanine Analogues via the Giese Reaction with Dehydroalanine Derivates

[Image: see text] Herein, we present the α-selective Giese reaction between pyranosyl/furanosyl bromides and dehydroalanine analogues, which provides access to a library of highly valuable α-C-glycosyl alanines. The key C-glycosyl radical is generated through photocatalysis by either the new generat...

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Autores principales: Poletti, Lorenzo, Massi, Alessandro, Ragno, Daniele, Droghetti, Federico, Natali, Mirco, De Risi, Carmela, Bortolini, Olga, Di Carmine, Graziano
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10334469/
https://www.ncbi.nlm.nih.gov/pubmed/37348204
http://dx.doi.org/10.1021/acs.orglett.3c01660

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