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Binding of Nitriles and Isonitriles to V(III) and Mo(III) Complexes: Ligand vs Metal Controlled Mechanism

[Image: see text] The synthesis and structures of nitrile complexes of V(N[(t)Bu]Ar)(3), 2 (Ar = 3,5-Me(2)C(6)H(3)), are described. Thermochemical and kinetic data for their formation were determined by variable temperature Fourier transform infrared (FTIR), calorimetry, and stopped-flow techniques....

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Detalles Bibliográficos
Autores principales:	Palluccio, Taryn D., Germain, Meaghan E., Marazzi, Marco, Temprado, Manuel, Silvia, Jared S., Müller, Peter, Cummins, Christopher C., Davis, Jack V., Serafim, Leonardo F., Captain, Burjor, Hoff, Carl D., Rybak-Akimova, Elena V.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10336974/ https://www.ncbi.nlm.nih.gov/pubmed/37377337 http://dx.doi.org/10.1021/acs.inorgchem.3c00595

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