Cargando…

Visible-Light/Nickel-Catalyzed Carboxylation of C(sp(2)) Bromides via Formate Activation

[Image: see text] A new visible-light-driven method for the carboxylation of (hetero)aryl/vinyl bromides has been developed using catalytic 4CzIPN, nickel, phenyl triflimide, and sodium formate as a carboxylation agent. Interestingly, we found catalytic phenyl triflimide plays an essential role in p...

Descripción completa

Detalles Bibliográficos
Autores principales:	Smith, Gavin C., Zhang, Drason H., Zhang, Wanli, Soliven, Abigail H., Wuest, William M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2023
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10337029/ https://www.ncbi.nlm.nih.gov/pubmed/37319431 http://dx.doi.org/10.1021/acs.joc.3c00895

Ejemplares similares

Visible-light-induced nickel-catalyzed α-hydroxytrifluoroethylation of alkyl carboxylic acids: Access to trifluoromethyl alkyl acyloins
por: Chen, Feng, et al.
Publicado: (2023)

Nickel-catalyzed reductive thiolation and selenylation of unactivated alkyl bromides
por: Fang, Yi, et al.
Publicado: (2018)

Visible-Light Photoredox Catalyzed Dehydrogenative Synthesis of Allylic Carboxylates from Styrenes
por: Liu, Yang, et al.
Publicado: (2021)

Visible-light photoredox-catalyzed umpolung carboxylation of carbonyl compounds with CO(2)
por: Cao, Guang-Mei, et al.
Publicado: (2021)

Nickel-Catalyzed Negishi Arylations of Propargylic Bromides: A Mechanistic Investigation
por: Schley, Nathan D., et al.
Publicado: (2014)

Nickel-catalyzed reductive coupling of unactivated alkyl bromides and aliphatic aldehydes
por: Cruz, Cole L., et al.
Publicado: (2021)

Intraligand Charge Transfer Enables Visible‐Light‐Mediated Nickel‐Catalyzed Cross‐Coupling Reactions
por: Cavedon, Cristian, et al.
Publicado: (2022)

Nickel-Catalyzed Addition of Aryl Bromides to Aldehydes To Form Hindered Secondary Alcohols
por: Garcia, Kevin J., et al.
Publicado: (2019)

Nickel-catalyzed reductive coupling of homoenolates and their higher homologues with unactivated alkyl bromides
por: Lin, Tingzhi, et al.
Publicado: (2020)

Amide Synthesis by Nickel/Photoredox‐Catalyzed Direct Carbamoylation of (Hetero)Aryl Bromides
por: Alandini, Nurtalya, et al.
Publicado: (2020)

Evidence for Photocatalyst Involvement in Oxidative Additions of Nickel-Catalyzed Carboxylate O-Arylations
por: Malik, Jamal A., et al.
Publicado: (2020)

Nickel-Catalyzed Enantioselective Electrochemical Reductive Cross-Coupling of Aryl Aziridines with Alkenyl Bromides
por: Hu, Xia, et al.
Publicado: (2023)

Nickel-catalyzed electrochemical carboxylation of unactivated aryl and alkyl halides with CO(2)
por: Sun, Guo-Quan, et al.
Publicado: (2021)

Replacing Conventional Carbon Nucleophiles with Electrophiles: Nickel-Catalyzed Reductive Alkylation of Aryl Bromides and Chlorides
por: Everson, Daniel A., et al.
Publicado: (2012)

Pd-catalyzed sp–sp(3) cross-coupling of benzyl bromides using lithium acetylides
por: Mondal, Anirban, et al.
Publicado: (2021)

Synergistic Visible-Light Photoredox/Nickel-Catalyzed Synthesis of Aliphatic Ketones via N–C Cleavage of Imides
por: Amani, Javad, et al.
Publicado: (2017)

Nickel Catalyzed Carbonylation/Carboxylation Sequence via Double CO(2) Incorporation
por: Giovanelli, Riccardo, et al.
Publicado: (2023)

Visible‐Light‐Promoted Iron‐Catalyzed C(sp(2))–C(sp(3)) Kumada Cross‐Coupling in Flow
por: Wei, Xiao‐Jing, et al.
Publicado: (2019)

Nickel-Catalyzed Reductive Conjugate Addition of Primary Alkyl Bromides to Enones To Form Silyl Enol Ethers
por: Huihui, Kierra M. M., et al.
Publicado: (2017)

Single-atom nickel terminating sp(2) and sp(3) nitride in polymeric carbon nitride for visible-light photocatalytic overall water splitting
por: Li, Yanrui, et al.
Publicado: (2021)

Visible light photoredox-catalyzed deoxygenation of alcohols
por: Rackl, Daniel, et al.
Publicado: (2014)

Synthesis of aryldifluoromethyl aryl ethers via nickel-catalyzed suzuki cross-coupling between aryloxydifluoromethyl bromides and boronic acids
por: Lu, Heng, et al.
Publicado: (2022)

Nickel-catalyzed enantioselective arylation of pyridine
por: Lutz, J. Patrick, et al.
Publicado: (2016)

Nickel-catalyzed cross-electrophile allylation of vinyl bromides and the modification of anti-tumour natural medicine β-elemene
por: Ye, Yang, et al.
Publicado: (2022)

Paired electrolysis-enabled nickel-catalyzed enantioselective reductive cross-coupling between α-chloroesters and aryl bromides
por: Liu, Dong, et al.
Publicado: (2022)

Nickel-catalysed cross-electrophile coupling of aryl bromides and primary alkyl bromides
por: Gao, Nanxing, et al.
Publicado: (2022)

Visible-Light Photoredox-Catalyzed Amidation of Benzylic Alcohols
por: Gaspa, Silvia, et al.
Publicado: (2020)

Visible‐Light Promoted C–O Bond Formation with an Integrated Carbon Nitride–Nickel Heterogeneous Photocatalyst
por: Vijeta, Arjun, et al.
Publicado: (2021)

Dual Visible Light Photoredox and Gold-Catalyzed Arylative Ring Expansion
por: Shu, Xing-zhong, et al.
Publicado: (2014)

C(sp(3))−C(sp(3)) bond formation via nickel-catalyzed deoxygenative homo-coupling of aldehydes/ketones mediated by hydrazine
por: Cao, Dawei, et al.
Publicado: (2021)

Visible-light-promoted and chlorophyll-catalyzed aerobic desulfurization of thioamides to amides
por: Yang, Zihui, et al.
Publicado: (2022)

Palladium-catalyzed benzylic C(sp(3))–H carbonylative arylation of azaarylmethyl amines with aryl bromides
por: Zhao, Haoqiang, et al.
Publicado: (2021)

Copper-catalyzed asymmetric sp(3) C–H arylation of tetrahydroisoquinoline mediated by a visible light photoredox catalyst
por: Querard, Pierre, et al.
Publicado: (2016)

Visible Light-Driven Reductive Azaarylation of Coumarin-3-carboxylic Acids
por: Kowalska, Ewelina, et al.
Publicado: (2022)

Pd-Catalyzed Nucleophilic Fluorination of Aryl Bromides
por: Lee, Hong Geun, et al.
Publicado: (2014)

Metal-Free ATRP Catalyzed by Visible Light in Continuous Flow
por: El Achi, Nassim, et al.
Publicado: (2020)

Selective Nickel- and Manganese-Catalyzed Decarboxylative Cross Coupling of Some α,β-Unsaturated Carboxylic Acids with Cyclic Ethers
por: Zhang, Jia-Xiang, et al.
Publicado: (2014)

Photoredox mediated nickel catalyzed C(sp(3))–H thiocarbonylation of ethers
por: Kang, Byungjoon, et al.
Publicado: (2017)

Visible-light-driven palladium-catalyzed Dowd–Beckwith ring expansion/C–C bond formation cascade
por: Chen, Li, et al.
Publicado: (2020)

Nickel nanoparticle-activated MoS(2) for efficient visible light photocatalytic hydrogen evolution
por: Shi, Xinying, et al.
Publicado: (2022)

Cannot write session to /tmp/vufind_sessions/sess_e1ioo3ce6ohh5c08t4d49oq24a