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Surmounting Byproduct Inhibition in an Intermolecular Catalytic Asymmetric Alkene Bromoesterification Reaction as Revealed by Kinetic Profiling

[Image: see text] Kinetic profiling has shown that a (DHQD)(2)PHAL-catalyzed intermolecular asymmetric alkene bromoesterification reaction is inhibited by primary amides, imides, hydantoins, and secondary cyclic amides, which are byproducts of common stoichiometric bromenium ion sources. Two approac...

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Detalles Bibliográficos
Autores principales: Braddock, D. Christopher, Lancaster, Ben M. J., Tighe, Christopher J., White, Andrew J. P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10337038/
https://www.ncbi.nlm.nih.gov/pubmed/37327488
http://dx.doi.org/10.1021/acs.joc.3c00672