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Thermally stable and color-tunable bi-activated (Dy(3+)/Eu(3+)) alkaline earth metasilicate phosphor for luminescent devices

A solid-state reaction methodology has been adopted to synthesize Dy(3+) (dysprosium)/Eu(3+) (europium) co-activated Na(4)Ca(4)Si(6)O(18) (NCMS) phosphors. The structural, morphological, and luminescence characteristics of the prepared materials have been investigated. The phase purity of the materi...

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Autores principales: Deepali, Jayasimhadri, M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10337746/
https://www.ncbi.nlm.nih.gov/pubmed/37449030
http://dx.doi.org/10.1039/d3ra03229a
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author Deepali
Jayasimhadri, M.
author_facet Deepali
Jayasimhadri, M.
author_sort Deepali
collection PubMed
description A solid-state reaction methodology has been adopted to synthesize Dy(3+) (dysprosium)/Eu(3+) (europium) co-activated Na(4)Ca(4)Si(6)O(18) (NCMS) phosphors. The structural, morphological, and luminescence characteristics of the prepared materials have been investigated. The phase purity of the material was confirmed by X-ray diffraction (XRD) by comparing the diffraction peaks with the JCPDS standard pattern (JCPDS card no. 75-1687). The photoluminescence (PL) spectra of NCMS phosphors activated with Dy(3+) and co-activated with Dy(3+) (sensitizer)/Eu(3+) (activator) ions were investigated. The as-prepared NCMS phosphors co-activated with Dy(3+)/Eu(3+) ions were excited with near-ultraviolet light (λ(ex) = 348 nm) and showed the utmost energy transfer of up to 97.80% from sensitizer to activator. Dexter and Reisfeld's approximation specifically confirms that the energy transfer from sensitizer to activator was through electric dipole–dipole interactions. The Dy(3+)-activated NCMS phosphor showed an illumination shift from yellow to red by varying the Eu(3+) ion concentration and colour tunability is also observed by altering the excitation energy. The emission intensity was sustained up to 92.21% at 423 K (∼150 °C), indicating an excellent thermal stability of the bi-activated NCMS phosphor. The Dy(3+)/Eu(3+) co-doped NCMS phosphors display excellent thermal stability with flexible color tunability to emerge as promising contenders in the field of lighting and display technologies.
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spelling pubmed-103377462023-07-13 Thermally stable and color-tunable bi-activated (Dy(3+)/Eu(3+)) alkaline earth metasilicate phosphor for luminescent devices Deepali Jayasimhadri, M. RSC Adv Chemistry A solid-state reaction methodology has been adopted to synthesize Dy(3+) (dysprosium)/Eu(3+) (europium) co-activated Na(4)Ca(4)Si(6)O(18) (NCMS) phosphors. The structural, morphological, and luminescence characteristics of the prepared materials have been investigated. The phase purity of the material was confirmed by X-ray diffraction (XRD) by comparing the diffraction peaks with the JCPDS standard pattern (JCPDS card no. 75-1687). The photoluminescence (PL) spectra of NCMS phosphors activated with Dy(3+) and co-activated with Dy(3+) (sensitizer)/Eu(3+) (activator) ions were investigated. The as-prepared NCMS phosphors co-activated with Dy(3+)/Eu(3+) ions were excited with near-ultraviolet light (λ(ex) = 348 nm) and showed the utmost energy transfer of up to 97.80% from sensitizer to activator. Dexter and Reisfeld's approximation specifically confirms that the energy transfer from sensitizer to activator was through electric dipole–dipole interactions. The Dy(3+)-activated NCMS phosphor showed an illumination shift from yellow to red by varying the Eu(3+) ion concentration and colour tunability is also observed by altering the excitation energy. The emission intensity was sustained up to 92.21% at 423 K (∼150 °C), indicating an excellent thermal stability of the bi-activated NCMS phosphor. The Dy(3+)/Eu(3+) co-doped NCMS phosphors display excellent thermal stability with flexible color tunability to emerge as promising contenders in the field of lighting and display technologies. The Royal Society of Chemistry 2023-07-12 /pmc/articles/PMC10337746/ /pubmed/37449030 http://dx.doi.org/10.1039/d3ra03229a Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Deepali
Jayasimhadri, M.
Thermally stable and color-tunable bi-activated (Dy(3+)/Eu(3+)) alkaline earth metasilicate phosphor for luminescent devices
title Thermally stable and color-tunable bi-activated (Dy(3+)/Eu(3+)) alkaline earth metasilicate phosphor for luminescent devices
title_full Thermally stable and color-tunable bi-activated (Dy(3+)/Eu(3+)) alkaline earth metasilicate phosphor for luminescent devices
title_fullStr Thermally stable and color-tunable bi-activated (Dy(3+)/Eu(3+)) alkaline earth metasilicate phosphor for luminescent devices
title_full_unstemmed Thermally stable and color-tunable bi-activated (Dy(3+)/Eu(3+)) alkaline earth metasilicate phosphor for luminescent devices
title_short Thermally stable and color-tunable bi-activated (Dy(3+)/Eu(3+)) alkaline earth metasilicate phosphor for luminescent devices
title_sort thermally stable and color-tunable bi-activated (dy(3+)/eu(3+)) alkaline earth metasilicate phosphor for luminescent devices
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10337746/
https://www.ncbi.nlm.nih.gov/pubmed/37449030
http://dx.doi.org/10.1039/d3ra03229a
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