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Synthesis and comparison of iso-structural f-block metal complexes (Ce, U, Np, Pu) featuring η(6)-arene interactions
Reaction of the terphenyl bis(anilide) ligand [{K(DME)(2)}(2)L(Ar)] (L(Ar) = {C(6)H(4)[(2,6-(i)Pr(2)C(6)H(3))NC(6)H(4)](2)}(2−)) with trivalent chloride “MCl(3)” salts (M = Ce, U, Np) yields two distinct products; neutral L(Ar)M(Cl)(THF) (1(M)) (M = Np, Ce), and the “-ate” complexes [K(DME)(2)][(L(A...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10337748/ https://www.ncbi.nlm.nih.gov/pubmed/37449075 http://dx.doi.org/10.1039/d3sc02194g |