A genuine germylene PGeP pincer ligand for formic acid dehydrogenation with iridium

We report an iridium system constructed around a long-tethered PGeP ligand that facilitates access to the less common germylene form, so far unreported for an ‘NHC-type’ Ge ligand. Its bonding is substantiated by computational studies and we have demonstrated its use for the catalytic dehydrogenatio...

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Detalles Bibliográficos
Autores principales: Fernández-Buenestado, Marta, Somerville, Rosie J., López-Serrano, Joaquín, Campos, Jesús
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10341385/
https://www.ncbi.nlm.nih.gov/pubmed/37358367
http://dx.doi.org/10.1039/d3cc02447d
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author Fernández-Buenestado, Marta
Somerville, Rosie J.
López-Serrano, Joaquín
Campos, Jesús
author_facet Fernández-Buenestado, Marta
Somerville, Rosie J.
López-Serrano, Joaquín
Campos, Jesús
author_sort Fernández-Buenestado, Marta
collection PubMed
description We report an iridium system constructed around a long-tethered PGeP ligand that facilitates access to the less common germylene form, so far unreported for an ‘NHC-type’ Ge ligand. Its bonding is substantiated by computational studies and we have demonstrated its use for the catalytic dehydrogenation of formic acid, highlighting the potential of this underdeveloped type of ligand.
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spelling pubmed-103413852023-07-14 A genuine germylene PGeP pincer ligand for formic acid dehydrogenation with iridium Fernández-Buenestado, Marta Somerville, Rosie J. López-Serrano, Joaquín Campos, Jesús Chem Commun (Camb) Chemistry We report an iridium system constructed around a long-tethered PGeP ligand that facilitates access to the less common germylene form, so far unreported for an ‘NHC-type’ Ge ligand. Its bonding is substantiated by computational studies and we have demonstrated its use for the catalytic dehydrogenation of formic acid, highlighting the potential of this underdeveloped type of ligand. The Royal Society of Chemistry 2023-06-16 /pmc/articles/PMC10341385/ /pubmed/37358367 http://dx.doi.org/10.1039/d3cc02447d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Fernández-Buenestado, Marta
Somerville, Rosie J.
López-Serrano, Joaquín
Campos, Jesús
A genuine germylene PGeP pincer ligand for formic acid dehydrogenation with iridium
title A genuine germylene PGeP pincer ligand for formic acid dehydrogenation with iridium
title_full A genuine germylene PGeP pincer ligand for formic acid dehydrogenation with iridium
title_fullStr A genuine germylene PGeP pincer ligand for formic acid dehydrogenation with iridium
title_full_unstemmed A genuine germylene PGeP pincer ligand for formic acid dehydrogenation with iridium
title_short A genuine germylene PGeP pincer ligand for formic acid dehydrogenation with iridium
title_sort genuine germylene pgep pincer ligand for formic acid dehydrogenation with iridium
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10341385/
https://www.ncbi.nlm.nih.gov/pubmed/37358367
http://dx.doi.org/10.1039/d3cc02447d
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