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Substitution of H Atoms in Unsaturated (Vinyl-Type) Carbocations by Cl or O Atoms

Introduction of Cl and O atoms into C(4)-vinyl carbocations was studied by X-ray diffraction analysis and IR spectroscopy. Chlorine atoms are weak electron acceptors in ordinary molecules but, within vinyl carbocations, manifest themselves as strong electron donors that accept a positive charge. The...

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Detalles Bibliográficos
Autores principales: Stoyanov, Evgenii S., Bagryanskaya, Irina Yu., Stoyanova, Irina V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10341854/
https://www.ncbi.nlm.nih.gov/pubmed/37445912
http://dx.doi.org/10.3390/ijms241310734