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Substitution of H Atoms in Unsaturated (Vinyl-Type) Carbocations by Cl or O Atoms
Introduction of Cl and O atoms into C(4)-vinyl carbocations was studied by X-ray diffraction analysis and IR spectroscopy. Chlorine atoms are weak electron acceptors in ordinary molecules but, within vinyl carbocations, manifest themselves as strong electron donors that accept a positive charge. The...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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MDPI
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10341854/ https://www.ncbi.nlm.nih.gov/pubmed/37445912 http://dx.doi.org/10.3390/ijms241310734 |