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Eco-Friendly Approach for the Construction of Superhydrophobic Coating on Stainless Steel Metal Based on Biological Metal–Organic Framework and Its Corrosion Resistance Performance
In this paper, we present a sustainable approach for the creation of superhydrophobic (SP) coating on a stainless-steel substrate based on a biological metal–organic framework (MOF). The MOF was synthesized using aspartic acid as a linker and copper ions as a core metal. Two SP coatings were well co...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10342640/ https://www.ncbi.nlm.nih.gov/pubmed/37445045 http://dx.doi.org/10.3390/ma16134728 |
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author | Almufarij, Rasmiah Saad Fetouh El Sayed, Howida Abouel Mohamed, Mohamed Elshahat |
author_facet | Almufarij, Rasmiah Saad Fetouh El Sayed, Howida Abouel Mohamed, Mohamed Elshahat |
author_sort | Almufarij, Rasmiah Saad |
collection | PubMed |
description | In this paper, we present a sustainable approach for the creation of superhydrophobic (SP) coating on a stainless-steel substrate based on a biological metal–organic framework (MOF). The MOF was synthesized using aspartic acid as a linker and copper ions as a core metal. Two SP coatings were well constructed on stainless steel utilizing electrodeposition of nickel (Ni) and nickel altered by MOF (Ni@Bio-MOF) coatings followed by soaking in a solution of stearic acid in ethanol. The results of Fourier transform infrared spectroscopy demonstrate that the stearic acid-grafted nickel coating (Ni@SA) and the stearic acid-grafted Ni@Bio-MOF composite (Ni@Bio-MOF@SA), were effectively deposited on the stainless steel. The wettability findings displayed that the water contact angle of Ni@SA and Ni@Cu-As MOF@SA are 160° ± 1.1°, and 168° ± 1.2°, respectively. The prepared SP coating was also found to be chemically and mechanically stable. The results show that the Ni@SA coating maintains SP characteristics in a pH range of 3–11 while the Ni@Cu-As MOF@SA coating retained SP characteristics in a pH range of 1–13. Additionally, the superhydrophobic Ni@SA coating demonstrated SP characteristics up to a length of abrasion equal to 1300 mm, while the Ni@Cu-As MOF@SA coating exhibited SP characteristics up to a length of abrasion equal to 2700 mm. Furthermore, the Ni@SA and Ni@Cu-As MOF@SA coatings exhibited significantly improved corrosion protection in a 0.5 M NaCl solution compared with bare stainless steel, with protection efficiencies of approximately 94% and 99%, respectively. The results of this study demonstrate that the proposed approach is a promising method for the fabrication of eco-friendly and corrosion-resistant SP coatings on stainless steel substrate. |
format | Online Article Text |
id | pubmed-10342640 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-103426402023-07-14 Eco-Friendly Approach for the Construction of Superhydrophobic Coating on Stainless Steel Metal Based on Biological Metal–Organic Framework and Its Corrosion Resistance Performance Almufarij, Rasmiah Saad Fetouh El Sayed, Howida Abouel Mohamed, Mohamed Elshahat Materials (Basel) Article In this paper, we present a sustainable approach for the creation of superhydrophobic (SP) coating on a stainless-steel substrate based on a biological metal–organic framework (MOF). The MOF was synthesized using aspartic acid as a linker and copper ions as a core metal. Two SP coatings were well constructed on stainless steel utilizing electrodeposition of nickel (Ni) and nickel altered by MOF (Ni@Bio-MOF) coatings followed by soaking in a solution of stearic acid in ethanol. The results of Fourier transform infrared spectroscopy demonstrate that the stearic acid-grafted nickel coating (Ni@SA) and the stearic acid-grafted Ni@Bio-MOF composite (Ni@Bio-MOF@SA), were effectively deposited on the stainless steel. The wettability findings displayed that the water contact angle of Ni@SA and Ni@Cu-As MOF@SA are 160° ± 1.1°, and 168° ± 1.2°, respectively. The prepared SP coating was also found to be chemically and mechanically stable. The results show that the Ni@SA coating maintains SP characteristics in a pH range of 3–11 while the Ni@Cu-As MOF@SA coating retained SP characteristics in a pH range of 1–13. Additionally, the superhydrophobic Ni@SA coating demonstrated SP characteristics up to a length of abrasion equal to 1300 mm, while the Ni@Cu-As MOF@SA coating exhibited SP characteristics up to a length of abrasion equal to 2700 mm. Furthermore, the Ni@SA and Ni@Cu-As MOF@SA coatings exhibited significantly improved corrosion protection in a 0.5 M NaCl solution compared with bare stainless steel, with protection efficiencies of approximately 94% and 99%, respectively. The results of this study demonstrate that the proposed approach is a promising method for the fabrication of eco-friendly and corrosion-resistant SP coatings on stainless steel substrate. MDPI 2023-06-30 /pmc/articles/PMC10342640/ /pubmed/37445045 http://dx.doi.org/10.3390/ma16134728 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Almufarij, Rasmiah Saad Fetouh El Sayed, Howida Abouel Mohamed, Mohamed Elshahat Eco-Friendly Approach for the Construction of Superhydrophobic Coating on Stainless Steel Metal Based on Biological Metal–Organic Framework and Its Corrosion Resistance Performance |
title | Eco-Friendly Approach for the Construction of Superhydrophobic Coating on Stainless Steel Metal Based on Biological Metal–Organic Framework and Its Corrosion Resistance Performance |
title_full | Eco-Friendly Approach for the Construction of Superhydrophobic Coating on Stainless Steel Metal Based on Biological Metal–Organic Framework and Its Corrosion Resistance Performance |
title_fullStr | Eco-Friendly Approach for the Construction of Superhydrophobic Coating on Stainless Steel Metal Based on Biological Metal–Organic Framework and Its Corrosion Resistance Performance |
title_full_unstemmed | Eco-Friendly Approach for the Construction of Superhydrophobic Coating on Stainless Steel Metal Based on Biological Metal–Organic Framework and Its Corrosion Resistance Performance |
title_short | Eco-Friendly Approach for the Construction of Superhydrophobic Coating on Stainless Steel Metal Based on Biological Metal–Organic Framework and Its Corrosion Resistance Performance |
title_sort | eco-friendly approach for the construction of superhydrophobic coating on stainless steel metal based on biological metal–organic framework and its corrosion resistance performance |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10342640/ https://www.ncbi.nlm.nih.gov/pubmed/37445045 http://dx.doi.org/10.3390/ma16134728 |
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