Metalation of a Hierarchical Self-Assembly Consisting of π-Stacked Cubes through Single-Crystal-to-Single-Crystal Transformation

Single-crystal-to-single-crystal metalation of organic ligands represents a novel method to prepare metal–organic complexes, but remains challenging. Herein, a hierarchical self-assembly {(H(12)L(8))·([N(C(2)H(5))(4)](+))(3)·(ClO(4)(−))(15)·(H(2)O)(32)} (1) (L = tris(2-benzimidazolylmethyl) amine) c...

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Autores principales: Wang, Bin, Nan, Zi-Ang, Liu, Jin, Lu, Zi-Xiu, Wang, Wei, Zhuo, Zhu, Li, Guo-Ling, Huang, You-Gui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10343287/
https://www.ncbi.nlm.nih.gov/pubmed/37446584
http://dx.doi.org/10.3390/molecules28134923
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author Wang, Bin
Nan, Zi-Ang
Liu, Jin
Lu, Zi-Xiu
Wang, Wei
Zhuo, Zhu
Li, Guo-Ling
Huang, You-Gui
author_facet Wang, Bin
Nan, Zi-Ang
Liu, Jin
Lu, Zi-Xiu
Wang, Wei
Zhuo, Zhu
Li, Guo-Ling
Huang, You-Gui
author_sort Wang, Bin
collection PubMed
description Single-crystal-to-single-crystal metalation of organic ligands represents a novel method to prepare metal–organic complexes, but remains challenging. Herein, a hierarchical self-assembly {(H(12)L(8))·([N(C(2)H(5))(4)](+))(3)·(ClO(4)(−))(15)·(H(2)O)(32)} (1) (L = tris(2-benzimidazolylmethyl) amine) consisting of π-stacked cubes which are assembled from eight partially protonated L ligands is obtained. By soaking the crystals of compound 1 in the aqueous solution of Co(SCN)(2), the ligands coordinate with Co(2+) ions stoichiometrically and ClO(4)(−) exchange with SCN(−) via single-crystal-to-single-crystal transformation, leading to {([CoSCNL](+))(8)·([NC(8)H(20)](+))(3)·(SCN)(11)·(H(2)O)(13)} (2).
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spelling pubmed-103432872023-07-14 Metalation of a Hierarchical Self-Assembly Consisting of π-Stacked Cubes through Single-Crystal-to-Single-Crystal Transformation Wang, Bin Nan, Zi-Ang Liu, Jin Lu, Zi-Xiu Wang, Wei Zhuo, Zhu Li, Guo-Ling Huang, You-Gui Molecules Communication Single-crystal-to-single-crystal metalation of organic ligands represents a novel method to prepare metal–organic complexes, but remains challenging. Herein, a hierarchical self-assembly {(H(12)L(8))·([N(C(2)H(5))(4)](+))(3)·(ClO(4)(−))(15)·(H(2)O)(32)} (1) (L = tris(2-benzimidazolylmethyl) amine) consisting of π-stacked cubes which are assembled from eight partially protonated L ligands is obtained. By soaking the crystals of compound 1 in the aqueous solution of Co(SCN)(2), the ligands coordinate with Co(2+) ions stoichiometrically and ClO(4)(−) exchange with SCN(−) via single-crystal-to-single-crystal transformation, leading to {([CoSCNL](+))(8)·([NC(8)H(20)](+))(3)·(SCN)(11)·(H(2)O)(13)} (2). MDPI 2023-06-22 /pmc/articles/PMC10343287/ /pubmed/37446584 http://dx.doi.org/10.3390/molecules28134923 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Wang, Bin
Nan, Zi-Ang
Liu, Jin
Lu, Zi-Xiu
Wang, Wei
Zhuo, Zhu
Li, Guo-Ling
Huang, You-Gui
Metalation of a Hierarchical Self-Assembly Consisting of π-Stacked Cubes through Single-Crystal-to-Single-Crystal Transformation
title Metalation of a Hierarchical Self-Assembly Consisting of π-Stacked Cubes through Single-Crystal-to-Single-Crystal Transformation
title_full Metalation of a Hierarchical Self-Assembly Consisting of π-Stacked Cubes through Single-Crystal-to-Single-Crystal Transformation
title_fullStr Metalation of a Hierarchical Self-Assembly Consisting of π-Stacked Cubes through Single-Crystal-to-Single-Crystal Transformation
title_full_unstemmed Metalation of a Hierarchical Self-Assembly Consisting of π-Stacked Cubes through Single-Crystal-to-Single-Crystal Transformation
title_short Metalation of a Hierarchical Self-Assembly Consisting of π-Stacked Cubes through Single-Crystal-to-Single-Crystal Transformation
title_sort metalation of a hierarchical self-assembly consisting of π-stacked cubes through single-crystal-to-single-crystal transformation
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10343287/
https://www.ncbi.nlm.nih.gov/pubmed/37446584
http://dx.doi.org/10.3390/molecules28134923
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