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Novel Corrosion Inhibitor for Carbon Steel in Acidic Solutions Based on α-Aminophosphonate (Chemical, Electrochemical, and Quantum Studies)

α-aminophosphonate (α-AP) is used as a novel corrosion inhibitor for carbon steel. The aggressive media applied in this study are HCl and H(2)SO(4) acid solutions. The findings indicate that the morphology of the α-AP compound is cubic, with particles ranging in size from 17 to 23 μm. FT-IR, (1)HNMR...

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Detalles Bibliográficos
Autores principales: Deyab, M. A., Abdeen, Marwa M., Hussien, Mohamed, E. El-Sayed, Ibrahim, Galhoum, Ahmed, El-Shamy, Omnia A. A., Abd Elfattah, Marwa
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10343381/
https://www.ncbi.nlm.nih.gov/pubmed/37446620
http://dx.doi.org/10.3390/molecules28134962
Descripción
Sumario:α-aminophosphonate (α-AP) is used as a novel corrosion inhibitor for carbon steel. The aggressive media applied in this study are HCl and H(2)SO(4) acid solutions. The findings indicate that the morphology of the α-AP compound is cubic, with particles ranging in size from 17 to 23 μm. FT-IR, (1)HNMR, (31)PNMR, and (13)CNMR analysis confirmed the synthesis of the α-AP molecule. It has been discovered that the compound α-AP plays an important role in inhibiting the corrosion of carbon steel in both HCl and H(2)SO(4) acids. This was identifiably inferred from the fact that the addition of α-AP compound decreased the corrosion rate. It is important to report that the maximum inhibition efficiency (92.4% for HCl and 95.7% for H(2)SO(4)) was obtained at 180 ppm. The primary factor affecting the rate at which steel specimens corrode in acidic electrolytes is the tendency of α-AP compounds to adsorb on the surface of steel through their heteroatoms (O, N, and P). This was verified by SEM/EDX results. The adsorption actually occurs through physical and chemical mechanisms via different active centers which are matched with the calculated quantum parameters. In addition, the adsorption of α-AP follows the Langmuir isotherm.