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A Generalized Polymer Precursor Ink Design for 3D Printing of Functional Metal Oxides
Three-dimensional-structured metal oxides have myriad applications for optoelectronic devices. Comparing to conventional lithography-based manufacturing methods which face significant challenges for 3D device architectures, additive manufacturing approaches such as direct ink writing offer convenien...
Autores principales: | , , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Springer Nature Singapore
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10344857/ https://www.ncbi.nlm.nih.gov/pubmed/37439950 http://dx.doi.org/10.1007/s40820-023-01147-w |
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author | Chen, Hehao Wang, Jizhe Peng, Siying Liu, Dongna Yan, Wei Shang, Xinggang Zhang, Boyu Yao, Yuan Hui, Yue Zhou, Nanjia |
author_facet | Chen, Hehao Wang, Jizhe Peng, Siying Liu, Dongna Yan, Wei Shang, Xinggang Zhang, Boyu Yao, Yuan Hui, Yue Zhou, Nanjia |
author_sort | Chen, Hehao |
collection | PubMed |
description | Three-dimensional-structured metal oxides have myriad applications for optoelectronic devices. Comparing to conventional lithography-based manufacturing methods which face significant challenges for 3D device architectures, additive manufacturing approaches such as direct ink writing offer convenient, on-demand manufacturing of 3D oxides with high resolutions down to sub-micrometer scales. However, the lack of a universal ink design strategy greatly limits the choices of printable oxides. Here, a universal, facile synthetic strategy is developed for direct ink writable polymer precursor inks based on metal-polymer coordination effect. Specifically, polyethyleneimine functionalized by ethylenediaminetetraacetic acid is employed as the polymer matrix for adsorbing targeted metal ions. Next, glucose is introduced as a crosslinker for endowing the polymer precursor inks with a thermosetting property required for 3D printing via the Maillard reaction. For demonstrations, binary (i.e., ZnO, CuO, In(2)O(3), Ga(2)O(3), TiO(2), and Y(2)O(3)) and ternary metal oxides (i.e., BaTiO(3) and SrTiO(3)) are printed into 3D architectures with sub-micrometer resolution by extruding the inks through ultrafine nozzles. Upon thermal crosslinking and pyrolysis, the 3D microarchitectures with woodpile geometries exhibit strong light-matter coupling in the mid-infrared region. The design strategy for printable inks opens a new pathway toward 3D-printed optoelectronic devices based on functional oxides. [Image: see text] SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1007/s40820-023-01147-w. |
format | Online Article Text |
id | pubmed-10344857 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | Springer Nature Singapore |
record_format | MEDLINE/PubMed |
spelling | pubmed-103448572023-07-15 A Generalized Polymer Precursor Ink Design for 3D Printing of Functional Metal Oxides Chen, Hehao Wang, Jizhe Peng, Siying Liu, Dongna Yan, Wei Shang, Xinggang Zhang, Boyu Yao, Yuan Hui, Yue Zhou, Nanjia Nanomicro Lett Article Three-dimensional-structured metal oxides have myriad applications for optoelectronic devices. Comparing to conventional lithography-based manufacturing methods which face significant challenges for 3D device architectures, additive manufacturing approaches such as direct ink writing offer convenient, on-demand manufacturing of 3D oxides with high resolutions down to sub-micrometer scales. However, the lack of a universal ink design strategy greatly limits the choices of printable oxides. Here, a universal, facile synthetic strategy is developed for direct ink writable polymer precursor inks based on metal-polymer coordination effect. Specifically, polyethyleneimine functionalized by ethylenediaminetetraacetic acid is employed as the polymer matrix for adsorbing targeted metal ions. Next, glucose is introduced as a crosslinker for endowing the polymer precursor inks with a thermosetting property required for 3D printing via the Maillard reaction. For demonstrations, binary (i.e., ZnO, CuO, In(2)O(3), Ga(2)O(3), TiO(2), and Y(2)O(3)) and ternary metal oxides (i.e., BaTiO(3) and SrTiO(3)) are printed into 3D architectures with sub-micrometer resolution by extruding the inks through ultrafine nozzles. Upon thermal crosslinking and pyrolysis, the 3D microarchitectures with woodpile geometries exhibit strong light-matter coupling in the mid-infrared region. The design strategy for printable inks opens a new pathway toward 3D-printed optoelectronic devices based on functional oxides. [Image: see text] SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1007/s40820-023-01147-w. Springer Nature Singapore 2023-07-13 /pmc/articles/PMC10344857/ /pubmed/37439950 http://dx.doi.org/10.1007/s40820-023-01147-w Text en © The Author(s) 2023 https://creativecommons.org/licenses/by/4.0/Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) . |
spellingShingle | Article Chen, Hehao Wang, Jizhe Peng, Siying Liu, Dongna Yan, Wei Shang, Xinggang Zhang, Boyu Yao, Yuan Hui, Yue Zhou, Nanjia A Generalized Polymer Precursor Ink Design for 3D Printing of Functional Metal Oxides |
title | A Generalized Polymer Precursor Ink Design for 3D Printing of Functional Metal Oxides |
title_full | A Generalized Polymer Precursor Ink Design for 3D Printing of Functional Metal Oxides |
title_fullStr | A Generalized Polymer Precursor Ink Design for 3D Printing of Functional Metal Oxides |
title_full_unstemmed | A Generalized Polymer Precursor Ink Design for 3D Printing of Functional Metal Oxides |
title_short | A Generalized Polymer Precursor Ink Design for 3D Printing of Functional Metal Oxides |
title_sort | generalized polymer precursor ink design for 3d printing of functional metal oxides |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10344857/ https://www.ncbi.nlm.nih.gov/pubmed/37439950 http://dx.doi.org/10.1007/s40820-023-01147-w |
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