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Photocatalyzed CO(2) reduction to CO by supramolecular photocatalysts made of Ru(II) photosensitizers and Re(I) catalytic subunits containing preformed CO(2)TEOA adducts

Two new supramolecular photocatalysts containing Ru(II) polypyridine units as light-harvesting photosensitizers and Re(I) polypyridine subunits as catalytic centers have been prepared. The new species, RuRe2A and Ru2ReA, contain catalytic Re(I) subunits coordinated by the preformed CO(2)TEOA adduct...

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Detalles Bibliográficos
Autores principales: Santoro, Antonio, Cancelliere, Ambra M., Kamogawa, Kei, Serroni, Scolastica, Puntoriero, Fausto, Tamaki, Yusuke, Campagna, Sebastiano, Ishitani, Osamu
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10344947/
https://www.ncbi.nlm.nih.gov/pubmed/37443197
http://dx.doi.org/10.1038/s41598-023-38411-3