Mechanistic Investigation of Ni-Catalyzed Reductive Cross-Coupling of Alkenyl and Benzyl Electrophiles

[Image: see text] Mechanistic investigations of the Ni-catalyzed asymmetric reductive alkenylation of N-hydroxyphthalimide (NHP) esters and benzylic chlorides are reported. Investigations of the redox properties of the Ni-bis(oxazoline) catalyst, the reaction kinetics, and mode of electrophile activ...

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Autores principales: Turro, Raymond F., Wahlman, Julie L.H., Tong, Z. Jaron, Chen, Xiahe, Yang, Miao, Chen, Emily P., Hong, Xin, Hadt, Ryan G., Houk, K. N., Yang, Yun-Fang, Reisman, Sarah E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10347553/
https://www.ncbi.nlm.nih.gov/pubmed/37358565
http://dx.doi.org/10.1021/jacs.3c02649

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