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Evidence for Ruthenium(II) Peralkene Complexes as Catalytic Species during the Isomerization of Terminal Alkenes in Solution
[Image: see text] The isomerization (chain-walking) reaction of terminal to internal alkenes is catalyzed by part-per-million amounts of practically any Ru source when the reaction is carried out with a neat terminal alkene. Here, we provide evidence that the soluble starting Ru sources evolve to ca...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2023
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10354743/ https://www.ncbi.nlm.nih.gov/pubmed/37393543 http://dx.doi.org/10.1021/acs.inorgchem.3c00967 |
| _version_ | 1785074988359876608 |
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| author | Sanz-Navarro, Sergio Ballesteros-Soberanas, Jordi Martínez-Castelló, Aarón Doménech-Carbó, Antonio Hernández-Garrido, Juan Carlos Cerón-Carrasco, Jose Pedro Mon, Marta Leyva-Pérez, Antonio |
| author_facet | Sanz-Navarro, Sergio Ballesteros-Soberanas, Jordi Martínez-Castelló, Aarón Doménech-Carbó, Antonio Hernández-Garrido, Juan Carlos Cerón-Carrasco, Jose Pedro Mon, Marta Leyva-Pérez, Antonio |
| author_sort | Sanz-Navarro, Sergio |
| collection | PubMed |
| description | [Image: see text] The isomerization (chain-walking) reaction of terminal to internal alkenes is catalyzed by part-per-million amounts of practically any Ru source when the reaction is carried out with a neat terminal alkene. Here, we provide evidence that the soluble starting Ru sources evolve to catalytically active peralkene Ru(II) species under reaction conditions. These species may also explain the isomerization products found during other Ru-catalyzed alkene processes, i.e., alkene metathesis reactions. A Finke–Watzky mechanism for catalyst formation is consistent with the evidence obtained. |
| format | Online Article Text |
| id | pubmed-10354743 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2023 |
| publisher | American Chemical Society |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-103547432023-07-20 Evidence for Ruthenium(II) Peralkene Complexes as Catalytic Species during the Isomerization of Terminal Alkenes in Solution Sanz-Navarro, Sergio Ballesteros-Soberanas, Jordi Martínez-Castelló, Aarón Doménech-Carbó, Antonio Hernández-Garrido, Juan Carlos Cerón-Carrasco, Jose Pedro Mon, Marta Leyva-Pérez, Antonio Inorg Chem [Image: see text] The isomerization (chain-walking) reaction of terminal to internal alkenes is catalyzed by part-per-million amounts of practically any Ru source when the reaction is carried out with a neat terminal alkene. Here, we provide evidence that the soluble starting Ru sources evolve to catalytically active peralkene Ru(II) species under reaction conditions. These species may also explain the isomerization products found during other Ru-catalyzed alkene processes, i.e., alkene metathesis reactions. A Finke–Watzky mechanism for catalyst formation is consistent with the evidence obtained. American Chemical Society 2023-07-03 /pmc/articles/PMC10354743/ /pubmed/37393543 http://dx.doi.org/10.1021/acs.inorgchem.3c00967 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/). |
| spellingShingle | Sanz-Navarro, Sergio Ballesteros-Soberanas, Jordi Martínez-Castelló, Aarón Doménech-Carbó, Antonio Hernández-Garrido, Juan Carlos Cerón-Carrasco, Jose Pedro Mon, Marta Leyva-Pérez, Antonio Evidence for Ruthenium(II) Peralkene Complexes as Catalytic Species during the Isomerization of Terminal Alkenes in Solution |
| title | Evidence for
Ruthenium(II) Peralkene Complexes as
Catalytic Species during the Isomerization of Terminal Alkenes in
Solution |
| title_full | Evidence for
Ruthenium(II) Peralkene Complexes as
Catalytic Species during the Isomerization of Terminal Alkenes in
Solution |
| title_fullStr | Evidence for
Ruthenium(II) Peralkene Complexes as
Catalytic Species during the Isomerization of Terminal Alkenes in
Solution |
| title_full_unstemmed | Evidence for
Ruthenium(II) Peralkene Complexes as
Catalytic Species during the Isomerization of Terminal Alkenes in
Solution |
| title_short | Evidence for
Ruthenium(II) Peralkene Complexes as
Catalytic Species during the Isomerization of Terminal Alkenes in
Solution |
| title_sort | evidence for
ruthenium(ii) peralkene complexes as
catalytic species during the isomerization of terminal alkenes in
solution |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10354743/ https://www.ncbi.nlm.nih.gov/pubmed/37393543 http://dx.doi.org/10.1021/acs.inorgchem.3c00967 |
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