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Potential Use of Melamine Phytate as a Flame-Retardant Additive in Chicken Feather-Containing Thermoplastic Polyurethane Biocomposites

[Image: see text] Using waste materials such as chicken feathers (CF) and biobased flame-retardant additives including melamine phytate (MPht) has become an effective approach for environmentally friendly and sustainable production in recent years. This study explores the flame retardant effectivene...

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Autores principales: Mutlu, Aysenur, Erdem, Aysegul, Dogan, Mehmet
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10357521/
https://www.ncbi.nlm.nih.gov/pubmed/37483238
http://dx.doi.org/10.1021/acsomega.3c01754
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author Mutlu, Aysenur
Erdem, Aysegul
Dogan, Mehmet
author_facet Mutlu, Aysenur
Erdem, Aysegul
Dogan, Mehmet
author_sort Mutlu, Aysenur
collection PubMed
description [Image: see text] Using waste materials such as chicken feathers (CF) and biobased flame-retardant additives including melamine phytate (MPht) has become an effective approach for environmentally friendly and sustainable production in recent years. This study explores the flame retardant effectiveness of MPht in thermoplastic polyurethane (TPU)-based biocomposites containing CF. The characterizations of the composites are performed through thermal gravimetric analysis (TGA), limiting oxygen index (LOI), vertical UL-94 (UL-94 V), and mass loss calorimetry (MLC) tests. According to the test results, the highest UL-94 V rating of V0, a LOI value of 29.4%, and the lowest peak heat release rate (pHRR) (110 Kw/m(2)) and total heat evolved (THE) (39 MJ/m(2)) values are obtained with the use of 20 wt % MPht. It is demonstrated that MPht acts as an effective flame-retardant filler through the formation of intumescent char in the condensed phase and flame dilution in the gas phase.
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spelling pubmed-103575212023-07-21 Potential Use of Melamine Phytate as a Flame-Retardant Additive in Chicken Feather-Containing Thermoplastic Polyurethane Biocomposites Mutlu, Aysenur Erdem, Aysegul Dogan, Mehmet ACS Omega [Image: see text] Using waste materials such as chicken feathers (CF) and biobased flame-retardant additives including melamine phytate (MPht) has become an effective approach for environmentally friendly and sustainable production in recent years. This study explores the flame retardant effectiveness of MPht in thermoplastic polyurethane (TPU)-based biocomposites containing CF. The characterizations of the composites are performed through thermal gravimetric analysis (TGA), limiting oxygen index (LOI), vertical UL-94 (UL-94 V), and mass loss calorimetry (MLC) tests. According to the test results, the highest UL-94 V rating of V0, a LOI value of 29.4%, and the lowest peak heat release rate (pHRR) (110 Kw/m(2)) and total heat evolved (THE) (39 MJ/m(2)) values are obtained with the use of 20 wt % MPht. It is demonstrated that MPht acts as an effective flame-retardant filler through the formation of intumescent char in the condensed phase and flame dilution in the gas phase. American Chemical Society 2023-07-04 /pmc/articles/PMC10357521/ /pubmed/37483238 http://dx.doi.org/10.1021/acsomega.3c01754 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Mutlu, Aysenur
Erdem, Aysegul
Dogan, Mehmet
Potential Use of Melamine Phytate as a Flame-Retardant Additive in Chicken Feather-Containing Thermoplastic Polyurethane Biocomposites
title Potential Use of Melamine Phytate as a Flame-Retardant Additive in Chicken Feather-Containing Thermoplastic Polyurethane Biocomposites
title_full Potential Use of Melamine Phytate as a Flame-Retardant Additive in Chicken Feather-Containing Thermoplastic Polyurethane Biocomposites
title_fullStr Potential Use of Melamine Phytate as a Flame-Retardant Additive in Chicken Feather-Containing Thermoplastic Polyurethane Biocomposites
title_full_unstemmed Potential Use of Melamine Phytate as a Flame-Retardant Additive in Chicken Feather-Containing Thermoplastic Polyurethane Biocomposites
title_short Potential Use of Melamine Phytate as a Flame-Retardant Additive in Chicken Feather-Containing Thermoplastic Polyurethane Biocomposites
title_sort potential use of melamine phytate as a flame-retardant additive in chicken feather-containing thermoplastic polyurethane biocomposites
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10357521/
https://www.ncbi.nlm.nih.gov/pubmed/37483238
http://dx.doi.org/10.1021/acsomega.3c01754
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