Harnessing Vinyl Acetate as an Acetylene Equivalent in Redox-Neutral Cp*Co(III)-Catalyzed C–H Activation/Annulation for the Synthesis of Isoquinolones and Pyridones

[Image: see text] We have developed Cp*Co(III)-catalyzed redox-neutral synthesis of 3,4-unsubstituted isoquinoline 1(2H)-ones at ambient temperature using N-chloroamides as a starting material. The reaction utilizes vinyl acetate as an inexpensive and benign acetylene surrogate. The N–Cl bond of the...

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Detalles Bibliográficos
Autores principales: Rana, Tamanna, Ghosh, Arijit, Aher, Yogesh N., Pawar, Amit B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10357576/
https://www.ncbi.nlm.nih.gov/pubmed/37483194
http://dx.doi.org/10.1021/acsomega.3c02352

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10357576/
https://www.ncbi.nlm.nih.gov/pubmed/37483194
http://dx.doi.org/10.1021/acsomega.3c02352

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