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Synthesis of Bis-tetraphenylethene as a Novel Turn-On Selective Zinc Sensor

[Image: see text] The main purpose of this study is the synthesis of novel fluorescent Bis-TPE and the investigation of its wide range of photochemical behaviors. For this purpose, initially, Bis-TPE was synthesized. Following this, the interactions of Bis-TPE with a wide range of ions were studied...

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Autores principales: Hussein, Abdullah Saleh, Lafzi, Ferruh, Kilic, Haydar, Bayindir, Sinan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10357583/
https://www.ncbi.nlm.nih.gov/pubmed/37483257
http://dx.doi.org/10.1021/acsomega.3c02955
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author Hussein, Abdullah Saleh
Lafzi, Ferruh
Kilic, Haydar
Bayindir, Sinan
author_facet Hussein, Abdullah Saleh
Lafzi, Ferruh
Kilic, Haydar
Bayindir, Sinan
author_sort Hussein, Abdullah Saleh
collection PubMed
description [Image: see text] The main purpose of this study is the synthesis of novel fluorescent Bis-TPE and the investigation of its wide range of photochemical behaviors. For this purpose, initially, Bis-TPE was synthesized. Following this, the interactions of Bis-TPE with a wide range of ions were studied in EtOH using ultraviolet–visible (UV–vis) and fluorescence spectroscopy. As a result of all UV–vis and fluorescence studies, it was determined that Bis-TPE showed turn-on sensor features against Zn(2+) ions. Moreover, the limit of detection (LOD) and K(a) values of Bis-TPE/Zn(2+) were calculated as 0.97 μM (970 nM) and 3.76 × 10(5) M(–1), respectively. Moreover, all reversal studies resulted in switchable on/off variation of the alternative addition of ZnCl(2) and [Bu(4)N]OH to Bis-TPE. This result also implies that the probe Bis-TPE also exhibits specific OH(–) sensor properties in the presence of zinc.
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spelling pubmed-103575832023-07-21 Synthesis of Bis-tetraphenylethene as a Novel Turn-On Selective Zinc Sensor Hussein, Abdullah Saleh Lafzi, Ferruh Kilic, Haydar Bayindir, Sinan ACS Omega [Image: see text] The main purpose of this study is the synthesis of novel fluorescent Bis-TPE and the investigation of its wide range of photochemical behaviors. For this purpose, initially, Bis-TPE was synthesized. Following this, the interactions of Bis-TPE with a wide range of ions were studied in EtOH using ultraviolet–visible (UV–vis) and fluorescence spectroscopy. As a result of all UV–vis and fluorescence studies, it was determined that Bis-TPE showed turn-on sensor features against Zn(2+) ions. Moreover, the limit of detection (LOD) and K(a) values of Bis-TPE/Zn(2+) were calculated as 0.97 μM (970 nM) and 3.76 × 10(5) M(–1), respectively. Moreover, all reversal studies resulted in switchable on/off variation of the alternative addition of ZnCl(2) and [Bu(4)N]OH to Bis-TPE. This result also implies that the probe Bis-TPE also exhibits specific OH(–) sensor properties in the presence of zinc. American Chemical Society 2023-07-03 /pmc/articles/PMC10357583/ /pubmed/37483257 http://dx.doi.org/10.1021/acsomega.3c02955 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Hussein, Abdullah Saleh
Lafzi, Ferruh
Kilic, Haydar
Bayindir, Sinan
Synthesis of Bis-tetraphenylethene as a Novel Turn-On Selective Zinc Sensor
title Synthesis of Bis-tetraphenylethene as a Novel Turn-On Selective Zinc Sensor
title_full Synthesis of Bis-tetraphenylethene as a Novel Turn-On Selective Zinc Sensor
title_fullStr Synthesis of Bis-tetraphenylethene as a Novel Turn-On Selective Zinc Sensor
title_full_unstemmed Synthesis of Bis-tetraphenylethene as a Novel Turn-On Selective Zinc Sensor
title_short Synthesis of Bis-tetraphenylethene as a Novel Turn-On Selective Zinc Sensor
title_sort synthesis of bis-tetraphenylethene as a novel turn-on selective zinc sensor
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10357583/
https://www.ncbi.nlm.nih.gov/pubmed/37483257
http://dx.doi.org/10.1021/acsomega.3c02955
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