Novel hydrophilic bistriazolyl-phenanthroline ligands with improved solubility and performance in An/Ln separations

Two novel bistriazolyl-phenanthroline (BTrzPhen) ligands, bearing benzene-sulphonate (DS-BTrzPhen) and amino-acidic (DAA-BTrzPhen) hydrophilizing moieties were developed and found to be more soluble in aqueous acidic media with improved selectivity for Am(iii) over Eu(iii) in solvent extraction stud...

Descripción completa

Detalles Bibliográficos
Autores principales: Wan, Yong Qiang, Hao, Huaixin, Yu, Lu, Wang, Zhi Peng, Mocilac, Pavle
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10358317/
https://www.ncbi.nlm.nih.gov/pubmed/37483667
http://dx.doi.org/10.1039/d3ra02707d
_version_ 1785075637690564608
author Wan, Yong Qiang
Hao, Huaixin
Yu, Lu
Wang, Zhi Peng
Mocilac, Pavle
author_facet Wan, Yong Qiang
Hao, Huaixin
Yu, Lu
Wang, Zhi Peng
Mocilac, Pavle
author_sort Wan, Yong Qiang
collection PubMed
description Two novel bistriazolyl-phenanthroline (BTrzPhen) ligands, bearing benzene-sulphonate (DS-BTrzPhen) and amino-acidic (DAA-BTrzPhen) hydrophilizing moieties were developed and found to be more soluble in aqueous acidic media with improved selectivity for Am(iii) over Eu(iii) in solvent extraction studies having SF(Eu/Am) values reaching >300. The remarkable activities of both ligands suggest that BTrzPhen ligands are generally still worth exploring and improving.
format Online
Article
Text
id pubmed-10358317
institution National Center for Biotechnology Information
language English
publishDate 2023
publisher The Royal Society of Chemistry
record_format MEDLINE/PubMed
spelling pubmed-103583172023-07-21 Novel hydrophilic bistriazolyl-phenanthroline ligands with improved solubility and performance in An/Ln separations Wan, Yong Qiang Hao, Huaixin Yu, Lu Wang, Zhi Peng Mocilac, Pavle RSC Adv Chemistry Two novel bistriazolyl-phenanthroline (BTrzPhen) ligands, bearing benzene-sulphonate (DS-BTrzPhen) and amino-acidic (DAA-BTrzPhen) hydrophilizing moieties were developed and found to be more soluble in aqueous acidic media with improved selectivity for Am(iii) over Eu(iii) in solvent extraction studies having SF(Eu/Am) values reaching >300. The remarkable activities of both ligands suggest that BTrzPhen ligands are generally still worth exploring and improving. The Royal Society of Chemistry 2023-07-20 /pmc/articles/PMC10358317/ /pubmed/37483667 http://dx.doi.org/10.1039/d3ra02707d Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Wan, Yong Qiang
Hao, Huaixin
Yu, Lu
Wang, Zhi Peng
Mocilac, Pavle
Novel hydrophilic bistriazolyl-phenanthroline ligands with improved solubility and performance in An/Ln separations
title Novel hydrophilic bistriazolyl-phenanthroline ligands with improved solubility and performance in An/Ln separations
title_full Novel hydrophilic bistriazolyl-phenanthroline ligands with improved solubility and performance in An/Ln separations
title_fullStr Novel hydrophilic bistriazolyl-phenanthroline ligands with improved solubility and performance in An/Ln separations
title_full_unstemmed Novel hydrophilic bistriazolyl-phenanthroline ligands with improved solubility and performance in An/Ln separations
title_short Novel hydrophilic bistriazolyl-phenanthroline ligands with improved solubility and performance in An/Ln separations
title_sort novel hydrophilic bistriazolyl-phenanthroline ligands with improved solubility and performance in an/ln separations
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10358317/
https://www.ncbi.nlm.nih.gov/pubmed/37483667
http://dx.doi.org/10.1039/d3ra02707d
work_keys_str_mv AT wanyongqiang novelhydrophilicbistriazolylphenanthrolineligandswithimprovedsolubilityandperformanceinanlnseparations
AT haohuaixin novelhydrophilicbistriazolylphenanthrolineligandswithimprovedsolubilityandperformanceinanlnseparations
AT yulu novelhydrophilicbistriazolylphenanthrolineligandswithimprovedsolubilityandperformanceinanlnseparations
AT wangzhipeng novelhydrophilicbistriazolylphenanthrolineligandswithimprovedsolubilityandperformanceinanlnseparations
AT mocilacpavle novelhydrophilicbistriazolylphenanthrolineligandswithimprovedsolubilityandperformanceinanlnseparations

Ejemplares similares