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Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents
Deep eutectic solvents (DESs) potential for the extraction of polyphenolic compounds (PC) from mango by-products (peel and seed) was evaluated. Ultrasound (US) and agitation were applied to evaluate the effects of solvent and extraction methodology. The extracts were characterized with antioxidant c...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Elsevier
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10360955/ https://www.ncbi.nlm.nih.gov/pubmed/37484239 http://dx.doi.org/10.1016/j.heliyon.2023.e16912 |
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author | Ojeda, Gonzalo A. Vallejos, Margarita M. Sgroppo, Sonia C. Sánchez-Moreno, Concepción de Ancos, Begoña |
author_facet | Ojeda, Gonzalo A. Vallejos, Margarita M. Sgroppo, Sonia C. Sánchez-Moreno, Concepción de Ancos, Begoña |
author_sort | Ojeda, Gonzalo A. |
collection | PubMed |
description | Deep eutectic solvents (DESs) potential for the extraction of polyphenolic compounds (PC) from mango by-products (peel and seed) was evaluated. Ultrasound (US) and agitation were applied to evaluate the effects of solvent and extraction methodology. The extracts were characterized with antioxidant capacity and HPLC-DAD profile. A theoretical study was performed using density functional theory and the QTAIM approach. β-alanine and choline chloride based DESs were effective to extract PC from peel and seed. Some DES increased PC extraction up to three times for peel (23.05 ± 1.22 mg/g DW) and up to five time for seeds (60.01 ± 1.40 mg/g DW). The PC profile varied with the solvent (DES vs EtOH/MeOH), procedure (US vs agitation) and material (peel or seed). Mangiferin extraction from peels was significantly increased with β-alanine based DES (676.08 ± 20.34 μg/gDW). The strength of H-bonds had a determining effect on the viscosity of DESs. The solute-solvent solvation energy was suitable to estimate the strength of H-bond interactions between DES and target compounds. This study demonstrates the remarkable capacity of DESs to extract PC from mango by-products and provides insights into the factors controlling extraction properties. |
format | Online Article Text |
id | pubmed-10360955 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | Elsevier |
record_format | MEDLINE/PubMed |
spelling | pubmed-103609552023-07-22 Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents Ojeda, Gonzalo A. Vallejos, Margarita M. Sgroppo, Sonia C. Sánchez-Moreno, Concepción de Ancos, Begoña Heliyon Research Article Deep eutectic solvents (DESs) potential for the extraction of polyphenolic compounds (PC) from mango by-products (peel and seed) was evaluated. Ultrasound (US) and agitation were applied to evaluate the effects of solvent and extraction methodology. The extracts were characterized with antioxidant capacity and HPLC-DAD profile. A theoretical study was performed using density functional theory and the QTAIM approach. β-alanine and choline chloride based DESs were effective to extract PC from peel and seed. Some DES increased PC extraction up to three times for peel (23.05 ± 1.22 mg/g DW) and up to five time for seeds (60.01 ± 1.40 mg/g DW). The PC profile varied with the solvent (DES vs EtOH/MeOH), procedure (US vs agitation) and material (peel or seed). Mangiferin extraction from peels was significantly increased with β-alanine based DES (676.08 ± 20.34 μg/gDW). The strength of H-bonds had a determining effect on the viscosity of DESs. The solute-solvent solvation energy was suitable to estimate the strength of H-bond interactions between DES and target compounds. This study demonstrates the remarkable capacity of DESs to extract PC from mango by-products and provides insights into the factors controlling extraction properties. Elsevier 2023-06-02 /pmc/articles/PMC10360955/ /pubmed/37484239 http://dx.doi.org/10.1016/j.heliyon.2023.e16912 Text en © 2023 The Authors https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Research Article Ojeda, Gonzalo A. Vallejos, Margarita M. Sgroppo, Sonia C. Sánchez-Moreno, Concepción de Ancos, Begoña Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents |
title | Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents |
title_full | Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents |
title_fullStr | Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents |
title_full_unstemmed | Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents |
title_short | Enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents |
title_sort | enhanced extraction of phenolic compounds from mango by-products using deep eutectic solvents |
topic | Research Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC10360955/ https://www.ncbi.nlm.nih.gov/pubmed/37484239 http://dx.doi.org/10.1016/j.heliyon.2023.e16912 |
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